Hydrothermal Synthesis, Crystal Structure and Magnetic Properties of Lithium Manganese Complex of Benzene-Hexacarboxylic Acid (Mellitic Acid)

Guang Xiang Liu; Heng Xu; Sadafumi Nishihara; Xiao Ming Ren

doi:10.1007/s10904-010-9375-4

Hydrothermal Synthesis, Crystal Structure and Magnetic Properties of Lithium Manganese Complex of Benzene-Hexacarboxylic Acid (Mellitic Acid)

Guang Xiang Liu, Heng Xu, Sadafumi Nishihara, Xiao Ming Ren

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

A new mellitate complex LiMn[C ₆(COO) ₆] _0.5(H ₂O) ₂ (1) has been synthesized by the reaction of mellitic acid and Mn(OAc) ₂·4H ₂O in the presence of LiOH·H ₂O. 1 was characterized by the elemental analyses, IR spectra, TGA and the single crystal X-ray diffraction. X-ray crystal structural analysis revealed that the Li cation has a distorted tetrahedral geometry, coordinated by three carboxylic oxygen atoms and one water molecule. The Mn cation is coordinated to one water molecule and five carboxylic oxygen atoms in a slightly distorted octahedral coordination geometry. The mellitate anions behave as a bridging ligand and link six lithium ions and eight manganese ions repeatedly to form an interesting three-dimensional metal-organic coordination polymer. Variable-temperature magnetic susceptibility measurements indicate the presence of antiferromagnetic behavior.

Original language	English
Pages (from-to)	564-569
Number of pages	6
Journal	Journal of Inorganic and Organometallic Polymers and Materials
Volume	20
Issue number	3
DOIs	https://doi.org/10.1007/s10904-010-9375-4
State	Published - 2010
Externally published	Yes

Keywords

Crystal structure
Lithium manganese complex
Magnetism
Multicarboxylate ligand

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10.1007/s10904-010-9375-4

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title = "Hydrothermal Synthesis, Crystal Structure and Magnetic Properties of Lithium Manganese Complex of Benzene-Hexacarboxylic Acid (Mellitic Acid)",

abstract = "A new mellitate complex LiMn[C 6(COO) 6] 0.5(H 2O) 2 (1) has been synthesized by the reaction of mellitic acid and Mn(OAc) 2·4H 2O in the presence of LiOH·H 2O. 1 was characterized by the elemental analyses, IR spectra, TGA and the single crystal X-ray diffraction. X-ray crystal structural analysis revealed that the Li cation has a distorted tetrahedral geometry, coordinated by three carboxylic oxygen atoms and one water molecule. The Mn cation is coordinated to one water molecule and five carboxylic oxygen atoms in a slightly distorted octahedral coordination geometry. The mellitate anions behave as a bridging ligand and link six lithium ions and eight manganese ions repeatedly to form an interesting three-dimensional metal-organic coordination polymer. Variable-temperature magnetic susceptibility measurements indicate the presence of antiferromagnetic behavior.",

keywords = "Crystal structure, Lithium manganese complex, Magnetism, Multicarboxylate ligand",

author = "Liu, {Guang Xiang} and Heng Xu and Sadafumi Nishihara and Ren, {Xiao Ming}",

year = "2010",

doi = "10.1007/s10904-010-9375-4",

language = "英语",

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T1 - Hydrothermal Synthesis, Crystal Structure and Magnetic Properties of Lithium Manganese Complex of Benzene-Hexacarboxylic Acid (Mellitic Acid)

AU - Liu, Guang Xiang

AU - Xu, Heng

AU - Nishihara, Sadafumi

AU - Ren, Xiao Ming

PY - 2010

Y1 - 2010

N2 - A new mellitate complex LiMn[C 6(COO) 6] 0.5(H 2O) 2 (1) has been synthesized by the reaction of mellitic acid and Mn(OAc) 2·4H 2O in the presence of LiOH·H 2O. 1 was characterized by the elemental analyses, IR spectra, TGA and the single crystal X-ray diffraction. X-ray crystal structural analysis revealed that the Li cation has a distorted tetrahedral geometry, coordinated by three carboxylic oxygen atoms and one water molecule. The Mn cation is coordinated to one water molecule and five carboxylic oxygen atoms in a slightly distorted octahedral coordination geometry. The mellitate anions behave as a bridging ligand and link six lithium ions and eight manganese ions repeatedly to form an interesting three-dimensional metal-organic coordination polymer. Variable-temperature magnetic susceptibility measurements indicate the presence of antiferromagnetic behavior.

AB - A new mellitate complex LiMn[C 6(COO) 6] 0.5(H 2O) 2 (1) has been synthesized by the reaction of mellitic acid and Mn(OAc) 2·4H 2O in the presence of LiOH·H 2O. 1 was characterized by the elemental analyses, IR spectra, TGA and the single crystal X-ray diffraction. X-ray crystal structural analysis revealed that the Li cation has a distorted tetrahedral geometry, coordinated by three carboxylic oxygen atoms and one water molecule. The Mn cation is coordinated to one water molecule and five carboxylic oxygen atoms in a slightly distorted octahedral coordination geometry. The mellitate anions behave as a bridging ligand and link six lithium ions and eight manganese ions repeatedly to form an interesting three-dimensional metal-organic coordination polymer. Variable-temperature magnetic susceptibility measurements indicate the presence of antiferromagnetic behavior.

KW - Crystal structure

KW - Lithium manganese complex

KW - Magnetism

KW - Multicarboxylate ligand

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DO - 10.1007/s10904-010-9375-4

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SN - 1574-1443

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JO - Journal of Inorganic and Organometallic Polymers and Materials

JF - Journal of Inorganic and Organometallic Polymers and Materials

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ER -

Hydrothermal Synthesis, Crystal Structure and Magnetic Properties of Lithium Manganese Complex of Benzene-Hexacarboxylic Acid (Mellitic Acid)

Abstract

Keywords

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