Hydrothermal synthesis, crystal structure and photoluminescence of a novel three-dimensional zinc(II) complex: [Zn2 (OH)(pyim)(BIPA)] n

Guang Xiang Liu; Yu Yong Xu; Rong Yi Huang; Xiao Ming Ren

Hydrothermal synthesis, crystal structure and photoluminescence of a novel three-dimensional zinc(II) complex: [Zn₂ (OH)(pyim)(BIPA)] _n

Guang Xiang Liu, Yu Yong Xu, Rong Yi Huang, Xiao Ming Ren

Anqing Nrormal University

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Hydrothermal reaction between 5-bromoisophthalic acid (H₂BIPA) and Zn(NO₃)2 ·6H₂O at the presence of the second ligand of 2-(2-pyridyl)imidazole (Hpyim) yields a new 3D metal-organic coordination polymer [Zn₂(OH)(pyim)(BIPA)]" (1), which has been characterized by single-crystal X-ray diffraction, elemental analysis, IB spectrum and thermal analysis. Complex 1 presents an α-Po net with 4′¹²6′⁵ topology constructed from l.el.ranuclear clusters and displays strong luminescent emission at room temperature. CCDC: 763940.

Original language	English
Pages (from-to)	1477-1481
Number of pages	5
Journal	Chinese Journal of Inorganic Chemistry
Volume	26
Issue number	8
State	Published - Aug 2010
Externally published	Yes

Keywords

Crystal structure
Luminescence
Multicarboxylate ligand
Zinc(II) complex

Cite this

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title = "Hydrothermal synthesis, crystal structure and photoluminescence of a novel three-dimensional zinc(II) complex: [Zn2 (OH)(pyim)(BIPA)] n",

abstract = "Hydrothermal reaction between 5-bromoisophthalic acid (H2BIPA) and Zn(NO3)2 ·6H2O at the presence of the second ligand of 2-(2-pyridyl)imidazole (Hpyim) yields a new 3D metal-organic coordination polymer [Zn2(OH)(pyim)(BIPA)]{"} (1), which has been characterized by single-crystal X-ray diffraction, elemental analysis, IB spectrum and thermal analysis. Complex 1 presents an α-Po net with 4′126′5 topology constructed from l.el.ranuclear clusters and displays strong luminescent emission at room temperature. CCDC: 763940.",

keywords = "Crystal structure, Luminescence, Multicarboxylate ligand, Zinc(II) complex",

author = "Liu, {Guang Xiang} and Xu, {Yu Yong} and Huang, {Rong Yi} and Ren, {Xiao Ming}",

year = "2010",

month = aug,

language = "英语",

volume = "26",

pages = "1477--1481",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

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TY - JOUR

T1 - Hydrothermal synthesis, crystal structure and photoluminescence of a novel three-dimensional zinc(II) complex

T2 - [Zn2 (OH)(pyim)(BIPA)] n

AU - Liu, Guang Xiang

AU - Xu, Yu Yong

AU - Huang, Rong Yi

AU - Ren, Xiao Ming

PY - 2010/8

Y1 - 2010/8

N2 - Hydrothermal reaction between 5-bromoisophthalic acid (H2BIPA) and Zn(NO3)2 ·6H2O at the presence of the second ligand of 2-(2-pyridyl)imidazole (Hpyim) yields a new 3D metal-organic coordination polymer [Zn2(OH)(pyim)(BIPA)]" (1), which has been characterized by single-crystal X-ray diffraction, elemental analysis, IB spectrum and thermal analysis. Complex 1 presents an α-Po net with 4′126′5 topology constructed from l.el.ranuclear clusters and displays strong luminescent emission at room temperature. CCDC: 763940.

AB - Hydrothermal reaction between 5-bromoisophthalic acid (H2BIPA) and Zn(NO3)2 ·6H2O at the presence of the second ligand of 2-(2-pyridyl)imidazole (Hpyim) yields a new 3D metal-organic coordination polymer [Zn2(OH)(pyim)(BIPA)]" (1), which has been characterized by single-crystal X-ray diffraction, elemental analysis, IB spectrum and thermal analysis. Complex 1 presents an α-Po net with 4′126′5 topology constructed from l.el.ranuclear clusters and displays strong luminescent emission at room temperature. CCDC: 763940.

KW - Crystal structure

KW - Luminescence

KW - Multicarboxylate ligand

KW - Zinc(II) complex

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M3 - 文章

AN - SCOPUS:77955222524

SN - 1001-4861

VL - 26

SP - 1477

EP - 1481

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 8

ER -

Hydrothermal synthesis, crystal structure and photoluminescence of a novel three-dimensional zinc(II) complex: [Zn₂ (OH)(pyim)(BIPA)] _n

Abstract

Keywords

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