Hydrothermal synthesis, crystal structure and photoluminescence of a new two-dimensional cadmium(II) complex [Cd3(HBTA)2(BIPA) 3]n

Guang Xiang Liu; Yu Yong Xu; Xiao Ming Ren

Hydrothermal synthesis, crystal structure and photoluminescence of a new two-dimensional cadmium(II) complex [Cd₃(HBTA)₂(BIPA) ₃]_n

Guang Xiang Liu, Yu Yong Xu, Xiao Ming Ren

Anqing Normal University

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The hydrothermal reactions of 5-bromoisophthalic acid (H₂BIPA), benzotriazole (HBTA) with Cd(NO₃)₂ · 4H ₂O in basified solvent gave rise to a coordination polymer [Cd ₃(HBTA)₂(BIPA)₃]_n (1), which has been characterized by elemental analysis, IR and single-crystal X-ray diffraction. Complex 1 presents a two-dimensional (2D) layer network containing the edge-sharing 1D-O-Cd-O chains through repetitions of the alternating arrangement of the Cd₃(CO₂)₆ cluster and displays strong luminescent emission at room temperature.

Original language	English
Pages (from-to)	1885-1889
Number of pages	5
Journal	Chinese Journal of Inorganic Chemistry
Volume	26
Issue number	10
State	Published - Oct 2010
Externally published	Yes

Keywords

Cadmium(II) complex
Crystal structure
Luminescence
Multicarboxylate ligand

Cite this

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title = "Hydrothermal synthesis, crystal structure and photoluminescence of a new two-dimensional cadmium(II) complex [Cd3(HBTA)2(BIPA) 3]n",

abstract = "The hydrothermal reactions of 5-bromoisophthalic acid (H2BIPA), benzotriazole (HBTA) with Cd(NO3)2 · 4H 2O in basified solvent gave rise to a coordination polymer [Cd 3(HBTA)2(BIPA)3]n (1), which has been characterized by elemental analysis, IR and single-crystal X-ray diffraction. Complex 1 presents a two-dimensional (2D) layer network containing the edge-sharing 1D-O-Cd-O chains through repetitions of the alternating arrangement of the Cd3(CO2)6 cluster and displays strong luminescent emission at room temperature.",

keywords = "Cadmium(II) complex, Crystal structure, Luminescence, Multicarboxylate ligand",

author = "Liu, {Guang Xiang} and Xu, {Yu Yong} and Ren, {Xiao Ming}",

year = "2010",

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language = "英语",

volume = "26",

pages = "1885--1889",

journal = "Chinese Journal of Inorganic Chemistry",

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T1 - Hydrothermal synthesis, crystal structure and photoluminescence of a new two-dimensional cadmium(II) complex [Cd3(HBTA)2(BIPA) 3]n

AU - Liu, Guang Xiang

AU - Xu, Yu Yong

AU - Ren, Xiao Ming

PY - 2010/10

Y1 - 2010/10

N2 - The hydrothermal reactions of 5-bromoisophthalic acid (H2BIPA), benzotriazole (HBTA) with Cd(NO3)2 · 4H 2O in basified solvent gave rise to a coordination polymer [Cd 3(HBTA)2(BIPA)3]n (1), which has been characterized by elemental analysis, IR and single-crystal X-ray diffraction. Complex 1 presents a two-dimensional (2D) layer network containing the edge-sharing 1D-O-Cd-O chains through repetitions of the alternating arrangement of the Cd3(CO2)6 cluster and displays strong luminescent emission at room temperature.

AB - The hydrothermal reactions of 5-bromoisophthalic acid (H2BIPA), benzotriazole (HBTA) with Cd(NO3)2 · 4H 2O in basified solvent gave rise to a coordination polymer [Cd 3(HBTA)2(BIPA)3]n (1), which has been characterized by elemental analysis, IR and single-crystal X-ray diffraction. Complex 1 presents a two-dimensional (2D) layer network containing the edge-sharing 1D-O-Cd-O chains through repetitions of the alternating arrangement of the Cd3(CO2)6 cluster and displays strong luminescent emission at room temperature.

KW - Cadmium(II) complex

KW - Crystal structure

KW - Luminescence

KW - Multicarboxylate ligand

UR - http://www.scopus.com/inward/record.url?scp=77957594090&partnerID=8YFLogxK

M3 - 文章

AN - SCOPUS:77957594090

SN - 1001-4861

VL - 26

SP - 1885

EP - 1889

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 10

ER -

Hydrothermal synthesis, crystal structure and photoluminescence of a new two-dimensional cadmium(II) complex [Cd₃(HBTA)₂(BIPA) ₃]_n

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Keywords

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