Identification of organic chlorines and iodines in the extracts from hydrotreated argonne premium coal residues

Lin Bing Sun; Zhi Min Zong; Jia Hui Kou; Jing Pei Cao; Gui Yun Yu; Wei Zhao; Bao Min Li; Chul Wee Lee; Ke Chang Xie; Xian Yong Wei

doi:10.1021/ef070091m

Identification of organic chlorines and iodines in the extracts from hydrotreated argonne premium coal residues

Lin Bing Sun, Zhi Min Zong, Jia Hui Kou, Jing Pei Cao, Gui Yun Yu, Wei Zhao, Bao Min Li, Chul Wee Lee, Ke Chang Xie, Xian Yong Wei

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

A solvent-insoluble fraction from three Arogonne Premium coals as reactants is used as reactants and the release of organic halogens (OHs) from the residues during noncatalytic and Ni-catalyzed hydrotreatments under relatively mild conditions is examined. The residues used as reactants are tetrahydrofuran/carbon disulfide insoluble fractions from three coals. After exhaustive extraction, THF and CS₂ remaining in the residues were removed by extraction with acetone. Result of the study showed that some organic chlorines and organic iodines are released from coal residues during noncatalytic and Nickel catalyzed hydrotreatment at 300°C. The OHs may be a moiety of organic macromolecular species in the Arogonne premium coals.

Original language	English
Pages (from-to)	2238-2239
Number of pages	2
Journal	Energy and Fuels
Volume	21
Issue number	4
DOIs	https://doi.org/10.1021/ef070091m
State	Published - Jul 2007
Externally published	Yes

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title = "Identification of organic chlorines and iodines in the extracts from hydrotreated argonne premium coal residues",

abstract = "A solvent-insoluble fraction from three Arogonne Premium coals as reactants is used as reactants and the release of organic halogens (OHs) from the residues during noncatalytic and Ni-catalyzed hydrotreatments under relatively mild conditions is examined. The residues used as reactants are tetrahydrofuran/carbon disulfide insoluble fractions from three coals. After exhaustive extraction, THF and CS2 remaining in the residues were removed by extraction with acetone. Result of the study showed that some organic chlorines and organic iodines are released from coal residues during noncatalytic and Nickel catalyzed hydrotreatment at 300°C. The OHs may be a moiety of organic macromolecular species in the Arogonne premium coals.",

author = "Sun, {Lin Bing} and Zong, {Zhi Min} and Kou, {Jia Hui} and Cao, {Jing Pei} and Yu, {Gui Yun} and Wei Zhao and Li, {Bao Min} and Lee, {Chul Wee} and Xie, {Ke Chang} and Wei, {Xian Yong}",

year = "2007",

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doi = "10.1021/ef070091m",

language = "英语",

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TY - JOUR

T1 - Identification of organic chlorines and iodines in the extracts from hydrotreated argonne premium coal residues

AU - Sun, Lin Bing

AU - Zong, Zhi Min

AU - Kou, Jia Hui

AU - Cao, Jing Pei

AU - Yu, Gui Yun

AU - Zhao, Wei

AU - Li, Bao Min

AU - Lee, Chul Wee

AU - Xie, Ke Chang

AU - Wei, Xian Yong

PY - 2007/7

Y1 - 2007/7

N2 - A solvent-insoluble fraction from three Arogonne Premium coals as reactants is used as reactants and the release of organic halogens (OHs) from the residues during noncatalytic and Ni-catalyzed hydrotreatments under relatively mild conditions is examined. The residues used as reactants are tetrahydrofuran/carbon disulfide insoluble fractions from three coals. After exhaustive extraction, THF and CS2 remaining in the residues were removed by extraction with acetone. Result of the study showed that some organic chlorines and organic iodines are released from coal residues during noncatalytic and Nickel catalyzed hydrotreatment at 300°C. The OHs may be a moiety of organic macromolecular species in the Arogonne premium coals.

AB - A solvent-insoluble fraction from three Arogonne Premium coals as reactants is used as reactants and the release of organic halogens (OHs) from the residues during noncatalytic and Ni-catalyzed hydrotreatments under relatively mild conditions is examined. The residues used as reactants are tetrahydrofuran/carbon disulfide insoluble fractions from three coals. After exhaustive extraction, THF and CS2 remaining in the residues were removed by extraction with acetone. Result of the study showed that some organic chlorines and organic iodines are released from coal residues during noncatalytic and Nickel catalyzed hydrotreatment at 300°C. The OHs may be a moiety of organic macromolecular species in the Arogonne premium coals.

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U2 - 10.1021/ef070091m

DO - 10.1021/ef070091m

M3 - 文章

AN - SCOPUS:34547734382

SN - 0887-0624

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SP - 2238

EP - 2239

JO - Energy and Fuels

JF - Energy and Fuels

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ER -

Identification of organic chlorines and iodines in the extracts from hydrotreated argonne premium coal residues

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