Influence of Fe powders replacing Cu powders on the thermal and mechanical properties of aluminate cementitious thermal energy storage materials at high temperature

Cost-effective thermal energy storage materials are vital to the application of solar thermal power plants. One focus of this paper is improving thermal and mechanical properties of the thermal energy storage materials; the second focus lies in reducing the investment cost. On the basis of aluminate cementitious composites with 1 wt% nano-SiO₂, 1 wt% nano-Cu and 15 wt% Cu powders, we introduced different wt% (0, 5, 10, and 15) of Fe powders to gradually replace 15 wt% Cu powders. The samples were heated at 105, 350, and 900 °C, respectively. As a result, when the content of Fe powders substitution was 10 wt%, volume heat capacity, thermal conductivity and compressive strength of the composites after heat-treatment at 900 °C were up to 2.38 MJ m⁻³ K⁻¹, 1.45 W m⁻¹ K⁻¹, and 73.8 MPa respectively, which were 26.6%, 26.1%, and 24.0% higher than those of the composites with 15 wt% Cu powders. At the same time, the investment of the composites with 10 wt% Fe powders substitution was reduced almost 62.0%, compared with that of the composites with 15 wt% Cu powders. In addition, XRD and MIP were employed to characteristic the mineral phases and the pore structures of the aluminate cementitious composites, respectively.