Isolation of neutral mono- and dinuclear gold complexes of cyclic (alkyl)(amino)carbenes

David S. Weinberger; Mohand Melaimi; Curtis E. Moore; Arnold L. Rheingold; Gernot Frenking; Paul Jerabek; Guy Bertrand

doi:10.1002/anie.201304820

Isolation of neutral mono- and dinuclear gold complexes of cyclic (alkyl)(amino)carbenes

David S. Weinberger, Mohand Melaimi, Curtis E. Moore, Arnold L. Rheingold, Gernot Frenking, Paul Jerabek, Guy Bertrand

Research output: Contribution to journal › Article › peer-review

105 Scopus citations

Abstract

The smallest pieces of gold! Thanks to the presence of two π-accepting cyclic (alkyl)(amino)carbenes (CAACs),complexes featuring one and two atoms of gold in the formal oxidation state of zero can be isolated.

Original language	English
Pages (from-to)	8964-8967
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	34
DOIs	https://doi.org/10.1002/anie.201304820
State	Published - 19 Aug 2013
Externally published	Yes

Keywords

carbenes
complexes
gold
zero oxidation state

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10.1002/anie.201304820

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title = "Isolation of neutral mono- and dinuclear gold complexes of cyclic (alkyl)(amino)carbenes",

abstract = "The smallest pieces of gold! Thanks to the presence of two π-accepting cyclic (alkyl)(amino)carbenes (CAACs),complexes featuring one and two atoms of gold in the formal oxidation state of zero can be isolated.",

keywords = "carbenes, complexes, gold, zero oxidation state",

author = "Weinberger, {David S.} and Mohand Melaimi and Moore, {Curtis E.} and Rheingold, {Arnold L.} and Gernot Frenking and Paul Jerabek and Guy Bertrand",

year = "2013",

month = aug,

day = "19",

doi = "10.1002/anie.201304820",

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T1 - Isolation of neutral mono- and dinuclear gold complexes of cyclic (alkyl)(amino)carbenes

AU - Weinberger, David S.

AU - Melaimi, Mohand

AU - Moore, Curtis E.

AU - Rheingold, Arnold L.

AU - Frenking, Gernot

AU - Jerabek, Paul

AU - Bertrand, Guy

PY - 2013/8/19

Y1 - 2013/8/19

N2 - The smallest pieces of gold! Thanks to the presence of two π-accepting cyclic (alkyl)(amino)carbenes (CAACs),complexes featuring one and two atoms of gold in the formal oxidation state of zero can be isolated.

AB - The smallest pieces of gold! Thanks to the presence of two π-accepting cyclic (alkyl)(amino)carbenes (CAACs),complexes featuring one and two atoms of gold in the formal oxidation state of zero can be isolated.

KW - carbenes

KW - complexes

KW - gold

KW - zero oxidation state

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U2 - 10.1002/anie.201304820

DO - 10.1002/anie.201304820

M3 - 文章

AN - SCOPUS:84882241032

SN - 1433-7851

VL - 52

SP - 8964

EP - 8967

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 34

ER -

Isolation of neutral mono- and dinuclear gold complexes of cyclic (alkyl)(amino)carbenes

Abstract

Keywords

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