Light-Induced Decarboxylative Phosphinylation

Zhen Zhen Liu; Chong Jing Zhang; Jian Ping Qu

doi:10.1021/acs.joc.4c03069

Light-Induced Decarboxylative Phosphinylation

Zhen Zhen Liu, Chong Jing Zhang, Jian Ping Qu

School of Chemistry and Moleculai Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

Abstract

A visible light-induced decarboxylative radical coupling between N-hydroxyphthalimide esters and phosphonites or phosphinites has been developed. The corresponding phosphinates or phosphine oxides could be obtained under mild conditions. No transition metals or toxic reagents were involved. This method provides a low-cost and practical alternative for synthesizing functionalized phosphinates or phosphine oxides.

Original language	English
Journal	Journal of Organic Chemistry
DOIs	https://doi.org/10.1021/acs.joc.4c03069
State	Accepted/In press - 2025

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10.1021/acs.joc.4c03069

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@article{833053fa1cd64a8d8931ab3a5e338d6d,

title = "Light-Induced Decarboxylative Phosphinylation",

abstract = "A visible light-induced decarboxylative radical coupling between N-hydroxyphthalimide esters and phosphonites or phosphinites has been developed. The corresponding phosphinates or phosphine oxides could be obtained under mild conditions. No transition metals or toxic reagents were involved. This method provides a low-cost and practical alternative for synthesizing functionalized phosphinates or phosphine oxides.",

author = "Liu, {Zhen Zhen} and Zhang, {Chong Jing} and Qu, {Jian Ping}",

note = "Publisher Copyright: {\textcopyright} 2025 American Chemical Society.",

year = "2025",

doi = "10.1021/acs.joc.4c03069",

language = "英语",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Light-Induced Decarboxylative Phosphinylation

AU - Liu, Zhen Zhen

AU - Zhang, Chong Jing

AU - Qu, Jian Ping

PY - 2025

Y1 - 2025

N2 - A visible light-induced decarboxylative radical coupling between N-hydroxyphthalimide esters and phosphonites or phosphinites has been developed. The corresponding phosphinates or phosphine oxides could be obtained under mild conditions. No transition metals or toxic reagents were involved. This method provides a low-cost and practical alternative for synthesizing functionalized phosphinates or phosphine oxides.

AB - A visible light-induced decarboxylative radical coupling between N-hydroxyphthalimide esters and phosphonites or phosphinites has been developed. The corresponding phosphinates or phosphine oxides could be obtained under mild conditions. No transition metals or toxic reagents were involved. This method provides a low-cost and practical alternative for synthesizing functionalized phosphinates or phosphine oxides.

UR - http://www.scopus.com/inward/record.url?scp=105004076274&partnerID=8YFLogxK

U2 - 10.1021/acs.joc.4c03069

DO - 10.1021/acs.joc.4c03069

M3 - 文章

AN - SCOPUS:105004076274

SN - 0022-3263

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

ER -

Light-Induced Decarboxylative Phosphinylation

Abstract

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