Low-temperature, highly selective, gas-phase oxidation of benzyl alcohol over mesoporous K-Cu-TiO2 with stable copper(I) oxidation state

Jie Fan; Yihu Dai; Yunlong Li; Nanfeng Zheng; Junfang Guo; Xiaoqing Yan; Galen D. Stucky

doi:10.1021/ja9032499

Low-temperature, highly selective, gas-phase oxidation of benzyl alcohol over mesoporous K-Cu-TiO₂ with stable copper(I) oxidation state

Jie Fan, Yihu Dai, Yunlong Li, Nanfeng Zheng, Junfang Guo, Xiaoqing Yan, Galen D. Stucky

Research output: Contribution to journal › Article › peer-review

128 Scopus citations

Abstract

(Graph Presented) A newly developed mesoporous mixed metal oxide (K-Cu-TiO₂) catalyst is capable of highly selective, gas-phase benzyl alcoholbenzaldehyde transformation at excellent yields (>99%) under surprisingly low temperatures (203°C, bp of benzyl alcohol). The low-temperature reaction conditions and integration of K and Cu(I) components into the TiO₂ matrix are of vital importance for the stabilization of an active Cu(I) oxidation state and resultant stable, excellent catalytic performance.

Original language	English
Pages (from-to)	15568-15569
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	43
DOIs	https://doi.org/10.1021/ja9032499
State	Published - 4 Nov 2009
Externally published	Yes

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10.1021/ja9032499

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title = "Low-temperature, highly selective, gas-phase oxidation of benzyl alcohol over mesoporous K-Cu-TiO2 with stable copper(I) oxidation state",

abstract = "(Graph Presented) A newly developed mesoporous mixed metal oxide (K-Cu-TiO2) catalyst is capable of highly selective, gas-phase benzyl alcoholbenzaldehyde transformation at excellent yields (>99%) under surprisingly low temperatures (203°C, bp of benzyl alcohol). The low-temperature reaction conditions and integration of K and Cu(I) components into the TiO2 matrix are of vital importance for the stabilization of an active Cu(I) oxidation state and resultant stable, excellent catalytic performance.",

author = "Jie Fan and Yihu Dai and Yunlong Li and Nanfeng Zheng and Junfang Guo and Xiaoqing Yan and Stucky, {Galen D.}",

year = "2009",

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doi = "10.1021/ja9032499",

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T1 - Low-temperature, highly selective, gas-phase oxidation of benzyl alcohol over mesoporous K-Cu-TiO2 with stable copper(I) oxidation state

AU - Fan, Jie

AU - Dai, Yihu

AU - Li, Yunlong

AU - Zheng, Nanfeng

AU - Guo, Junfang

AU - Yan, Xiaoqing

AU - Stucky, Galen D.

PY - 2009/11/4

Y1 - 2009/11/4

N2 - (Graph Presented) A newly developed mesoporous mixed metal oxide (K-Cu-TiO2) catalyst is capable of highly selective, gas-phase benzyl alcoholbenzaldehyde transformation at excellent yields (>99%) under surprisingly low temperatures (203°C, bp of benzyl alcohol). The low-temperature reaction conditions and integration of K and Cu(I) components into the TiO2 matrix are of vital importance for the stabilization of an active Cu(I) oxidation state and resultant stable, excellent catalytic performance.

AB - (Graph Presented) A newly developed mesoporous mixed metal oxide (K-Cu-TiO2) catalyst is capable of highly selective, gas-phase benzyl alcoholbenzaldehyde transformation at excellent yields (>99%) under surprisingly low temperatures (203°C, bp of benzyl alcohol). The low-temperature reaction conditions and integration of K and Cu(I) components into the TiO2 matrix are of vital importance for the stabilization of an active Cu(I) oxidation state and resultant stable, excellent catalytic performance.

UR - http://www.scopus.com/inward/record.url?scp=70350635640&partnerID=8YFLogxK

U2 - 10.1021/ja9032499

DO - 10.1021/ja9032499

M3 - 文章

AN - SCOPUS:70350635640

SN - 0002-7863

VL - 131

SP - 15568

EP - 15569

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 43

ER -

Low-temperature, highly selective, gas-phase oxidation of benzyl alcohol over mesoporous K-Cu-TiO₂ with stable copper(I) oxidation state

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