Modulating the basicity of Zn-MOF-74: Via cation exchange with calcium ions

Zhuxiu Zhang; Yue Xiao; Mifen Cui; Jihai Tang; Zhaoyang Fei; Qing Liu; Xian Chen; Xu Qiao

doi:10.1039/c9dt03332g

Modulating the basicity of Zn-MOF-74: Via cation exchange with calcium ions

Zhuxiu Zhang, Yue Xiao, Mifen Cui, Jihai Tang, Zhaoyang Fei, Qing Liu, Xian Chen, Xu Qiao

COLLEGE OF CHEMICAL ENGINEERING

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

The fine-tuning of metal-based molecular building blocks in Zn-MOF-74 through post-synthetic cation exchange with Ca2+ significantly enhances its basicity and corresponding catalytic performance. The resulting material, exemplified by Ca/Zn-MOF-74, is shown through Knoevenagel condensation to give an improved product yield over the parent Zn-MOF-74 and Ni/Zn-MOF-74.

Original language	English
Pages (from-to)	14971-14974
Number of pages	4
Journal	Dalton Transactions
Volume	48
Issue number	40
DOIs	https://doi.org/10.1039/c9dt03332g
State	Published - 2019

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abstract = "The fine-tuning of metal-based molecular building blocks in Zn-MOF-74 through post-synthetic cation exchange with Ca2+ significantly enhances its basicity and corresponding catalytic performance. The resulting material, exemplified by Ca/Zn-MOF-74, is shown through Knoevenagel condensation to give an improved product yield over the parent Zn-MOF-74 and Ni/Zn-MOF-74.",

author = "Zhuxiu Zhang and Yue Xiao and Mifen Cui and Jihai Tang and Zhaoyang Fei and Qing Liu and Xian Chen and Xu Qiao",

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T1 - Modulating the basicity of Zn-MOF-74

T2 - Via cation exchange with calcium ions

AU - Zhang, Zhuxiu

AU - Xiao, Yue

AU - Cui, Mifen

AU - Tang, Jihai

AU - Fei, Zhaoyang

AU - Liu, Qing

AU - Chen, Xian

AU - Qiao, Xu

PY - 2019

Y1 - 2019

N2 - The fine-tuning of metal-based molecular building blocks in Zn-MOF-74 through post-synthetic cation exchange with Ca2+ significantly enhances its basicity and corresponding catalytic performance. The resulting material, exemplified by Ca/Zn-MOF-74, is shown through Knoevenagel condensation to give an improved product yield over the parent Zn-MOF-74 and Ni/Zn-MOF-74.

AB - The fine-tuning of metal-based molecular building blocks in Zn-MOF-74 through post-synthetic cation exchange with Ca2+ significantly enhances its basicity and corresponding catalytic performance. The resulting material, exemplified by Ca/Zn-MOF-74, is shown through Knoevenagel condensation to give an improved product yield over the parent Zn-MOF-74 and Ni/Zn-MOF-74.

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U2 - 10.1039/c9dt03332g

DO - 10.1039/c9dt03332g

M3 - 文章

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AN - SCOPUS:85073183931

SN - 1477-9226

VL - 48

SP - 14971

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JO - Dalton Transactions

JF - Dalton Transactions

IS - 40

ER -

Modulating the basicity of Zn-MOF-74: Via cation exchange with calcium ions

Abstract

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