Oxidative coupling of methane over Na-W-Mn-Zr-S-P/SiO2 catalyst: Effect of S, P addition on the catalytic performance

Fengqiu Chen; Wen Zheng; Ning Zhu; Dang Guo Cheng; Xiaoli Zhan

doi:10.1007/s10562-008-9571-9

Oxidative coupling of methane over Na-W-Mn-Zr-S-P/SiO₂ catalyst: Effect of S, P addition on the catalytic performance

Fengqiu Chen, Wen Zheng, Ning Zhu, Dang Guo Cheng, Xiaoli Zhan

Zhejiang University

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

The multi-component catalysts we prepared exhibited high performance for the oxidative coupling of methane. The highest activity of catalysts was obtained over the Na-W-Mn-Zr-S-P/SiO₂ at the temperature of 1,023 K, on which the C₂ yield was 23.5% at the methane conversion of 43.8%. XRD and XPS results showed the S, P addition could lead to the increase of lattice oxygen concentration and the formation of phase such as Na ₂SO₄, Na₂Zr(PO₄)₂ on the catalysts. These phases play great roles in activity of the catalysts system.

Original language	English
Pages (from-to)	348-351
Number of pages	4
Journal	Catalysis Letters
Volume	125
Issue number	3-4
DOIs	https://doi.org/10.1007/s10562-008-9571-9
State	Published - Oct 2008
Externally published	Yes

Keywords

Na-W-Mn-Zr-S-P/SiO
Oxidative coupling of methane
Phosphorus
Sulfur

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10.1007/s10562-008-9571-9

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title = "Oxidative coupling of methane over Na-W-Mn-Zr-S-P/SiO2 catalyst: Effect of S, P addition on the catalytic performance",

abstract = "The multi-component catalysts we prepared exhibited high performance for the oxidative coupling of methane. The highest activity of catalysts was obtained over the Na-W-Mn-Zr-S-P/SiO2 at the temperature of 1,023 K, on which the C2 yield was 23.5% at the methane conversion of 43.8%. XRD and XPS results showed the S, P addition could lead to the increase of lattice oxygen concentration and the formation of phase such as Na 2SO4, Na2Zr(PO4)2 on the catalysts. These phases play great roles in activity of the catalysts system.",

keywords = "Na-W-Mn-Zr-S-P/SiO, Oxidative coupling of methane, Phosphorus, Sulfur",

author = "Fengqiu Chen and Wen Zheng and Ning Zhu and Cheng, {Dang Guo} and Xiaoli Zhan",

year = "2008",

month = oct,

doi = "10.1007/s10562-008-9571-9",

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volume = "125",

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journal = "Catalysis Letters",

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TY - JOUR

T1 - Oxidative coupling of methane over Na-W-Mn-Zr-S-P/SiO2 catalyst

T2 - Effect of S, P addition on the catalytic performance

AU - Chen, Fengqiu

AU - Zheng, Wen

AU - Zhu, Ning

AU - Cheng, Dang Guo

AU - Zhan, Xiaoli

PY - 2008/10

Y1 - 2008/10

N2 - The multi-component catalysts we prepared exhibited high performance for the oxidative coupling of methane. The highest activity of catalysts was obtained over the Na-W-Mn-Zr-S-P/SiO2 at the temperature of 1,023 K, on which the C2 yield was 23.5% at the methane conversion of 43.8%. XRD and XPS results showed the S, P addition could lead to the increase of lattice oxygen concentration and the formation of phase such as Na 2SO4, Na2Zr(PO4)2 on the catalysts. These phases play great roles in activity of the catalysts system.

AB - The multi-component catalysts we prepared exhibited high performance for the oxidative coupling of methane. The highest activity of catalysts was obtained over the Na-W-Mn-Zr-S-P/SiO2 at the temperature of 1,023 K, on which the C2 yield was 23.5% at the methane conversion of 43.8%. XRD and XPS results showed the S, P addition could lead to the increase of lattice oxygen concentration and the formation of phase such as Na 2SO4, Na2Zr(PO4)2 on the catalysts. These phases play great roles in activity of the catalysts system.

KW - Na-W-Mn-Zr-S-P/SiO

KW - Oxidative coupling of methane

KW - Phosphorus

KW - Sulfur

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DO - 10.1007/s10562-008-9571-9

M3 - 文章

AN - SCOPUS:52349107650

SN - 1011-372X

VL - 125

SP - 348

EP - 351

JO - Catalysis Letters

JF - Catalysis Letters

IS - 3-4

ER -

Oxidative coupling of methane over Na-W-Mn-Zr-S-P/SiO₂ catalyst: Effect of S, P addition on the catalytic performance

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Keywords

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