Palladium-catalyzed regioselective hydrosulfonylation of allenes with sulfinic acids

Luan Ying Li; Bo Rong Leng; Jia Zhuo Li; Qing Quan Liu; Jianguang Yu; Ping Wei; De Cai Wang; Yi Long Zhu

doi:10.1039/d1ra09036d

Palladium-catalyzed regioselective hydrosulfonylation of allenes with sulfinic acids

Luan Ying Li, Bo Rong Leng, Jia Zhuo Li, Qing Quan Liu, Jianguang Yu, Ping Wei, De Cai Wang, Yi Long Zhu

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6 Scopus citations

Abstract

An atom-economic method of preparing allylic sulfones via hydrosulfonylation of allenes with sulfinic acids under Pd(0)-catalysis was reported. This process has a high degree of regio- and stereoselectivity, and provides the target product with a moderate to excellent yield. A wide range of nitrogen- or oxygen-containing linear E-allylic sulfones have been synthesized. With the support of experimental research, a possible mechanism was proposed.

Original language	English
Pages (from-to)	8443-8448
Number of pages	6
Journal	RSC Advances
Volume	12
Issue number	14
DOIs	https://doi.org/10.1039/d1ra09036d
State	Published - 18 Mar 2022

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title = "Palladium-catalyzed regioselective hydrosulfonylation of allenes with sulfinic acids",

abstract = "An atom-economic method of preparing allylic sulfones via hydrosulfonylation of allenes with sulfinic acids under Pd(0)-catalysis was reported. This process has a high degree of regio- and stereoselectivity, and provides the target product with a moderate to excellent yield. A wide range of nitrogen- or oxygen-containing linear E-allylic sulfones have been synthesized. With the support of experimental research, a possible mechanism was proposed.",

author = "Li, {Luan Ying} and Leng, {Bo Rong} and Li, {Jia Zhuo} and Liu, {Qing Quan} and Jianguang Yu and Ping Wei and Wang, {De Cai} and Zhu, {Yi Long}",

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T1 - Palladium-catalyzed regioselective hydrosulfonylation of allenes with sulfinic acids

AU - Li, Luan Ying

AU - Leng, Bo Rong

AU - Li, Jia Zhuo

AU - Liu, Qing Quan

AU - Yu, Jianguang

AU - Wei, Ping

AU - Wang, De Cai

AU - Zhu, Yi Long

PY - 2022/3/18

Y1 - 2022/3/18

N2 - An atom-economic method of preparing allylic sulfones via hydrosulfonylation of allenes with sulfinic acids under Pd(0)-catalysis was reported. This process has a high degree of regio- and stereoselectivity, and provides the target product with a moderate to excellent yield. A wide range of nitrogen- or oxygen-containing linear E-allylic sulfones have been synthesized. With the support of experimental research, a possible mechanism was proposed.

AB - An atom-economic method of preparing allylic sulfones via hydrosulfonylation of allenes with sulfinic acids under Pd(0)-catalysis was reported. This process has a high degree of regio- and stereoselectivity, and provides the target product with a moderate to excellent yield. A wide range of nitrogen- or oxygen-containing linear E-allylic sulfones have been synthesized. With the support of experimental research, a possible mechanism was proposed.

UR - http://www.scopus.com/inward/record.url?scp=85127329600&partnerID=8YFLogxK

U2 - 10.1039/d1ra09036d

DO - 10.1039/d1ra09036d

M3 - 文章

AN - SCOPUS:85127329600

SN - 2046-2069

VL - 12

SP - 8443

EP - 8448

JO - RSC Advances

JF - RSC Advances

IS - 14

ER -

Palladium-catalyzed regioselective hydrosulfonylation of allenes with sulfinic acids

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