Practical synthesis of 1,5-dimethyl substituted conjugated polyenes from geranyl acetate

Yu Jun Zhao; Teck Peng Loh

doi:10.1016/j.tet.2008.03.094

Practical synthesis of 1,5-dimethyl substituted conjugated polyenes from geranyl acetate

Yu Jun Zhao, Teck Peng Loh

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A protocol to synthesize 1,5-dimethyl substituted conjugated polyenes via dehydrogenation of geranyl acetate was established. C₅ unit elongation to multi-1,5-dimethyl substituted conjugated polyenes was also achieved via Horner-Wadsworth-Emmons olefination in good yields and good selectivities.

Original language	English
Pages (from-to)	4972-4978
Number of pages	7
Journal	Tetrahedron
Volume	64
Issue number	22
DOIs	https://doi.org/10.1016/j.tet.2008.03.094
State	Published - 26 May 2008
Externally published	Yes

Keywords

Conjugated
Elimination
Natural Products
Olefination
Terpenoids

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10.1016/j.tet.2008.03.094

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title = "Practical synthesis of 1,5-dimethyl substituted conjugated polyenes from geranyl acetate",

abstract = "A protocol to synthesize 1,5-dimethyl substituted conjugated polyenes via dehydrogenation of geranyl acetate was established. C5 unit elongation to multi-1,5-dimethyl substituted conjugated polyenes was also achieved via Horner-Wadsworth-Emmons olefination in good yields and good selectivities.",

keywords = "Conjugated, Elimination, Natural Products, Olefination, Terpenoids",

author = "Zhao, {Yu Jun} and Loh, {Teck Peng}",

year = "2008",

month = may,

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doi = "10.1016/j.tet.2008.03.094",

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AU - Zhao, Yu Jun

AU - Loh, Teck Peng

PY - 2008/5/26

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N2 - A protocol to synthesize 1,5-dimethyl substituted conjugated polyenes via dehydrogenation of geranyl acetate was established. C5 unit elongation to multi-1,5-dimethyl substituted conjugated polyenes was also achieved via Horner-Wadsworth-Emmons olefination in good yields and good selectivities.

AB - A protocol to synthesize 1,5-dimethyl substituted conjugated polyenes via dehydrogenation of geranyl acetate was established. C5 unit elongation to multi-1,5-dimethyl substituted conjugated polyenes was also achieved via Horner-Wadsworth-Emmons olefination in good yields and good selectivities.

KW - Conjugated

KW - Elimination

KW - Natural Products

KW - Olefination

KW - Terpenoids

UR - http://www.scopus.com/inward/record.url?scp=42749089757&partnerID=8YFLogxK

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DO - 10.1016/j.tet.2008.03.094

M3 - 文章

AN - SCOPUS:42749089757

SN - 0040-4020

VL - 64

SP - 4972

EP - 4978

JO - Tetrahedron

JF - Tetrahedron

IS - 22

ER -

Practical synthesis of 1,5-dimethyl substituted conjugated polyenes from geranyl acetate

Abstract

Keywords

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