TY - JOUR
T1 - Recent progress in advanced organosulfur cathode materials for rechargeable lithium batteries
AU - Zhang, Qianyu
AU - Ma, Quanwei
AU - Wang, Rui
AU - Liu, Zixiang
AU - Zhai, Yunming
AU - Pang, Yanrui
AU - Tang, Ying
AU - Wang, Qian
AU - Wu, Kaipeng
AU - Wu, Hao
AU - Zhang, Yun
AU - Zhang, Longhai
AU - Zhang, Chaofeng
AU - Fu, Lijun
AU - Eliseeva, Svetlana
AU - Kondratiev, Veniamin
AU - Wu, Yuping
N1 - Publisher Copyright:
© 2023 Elsevier Ltd
PY - 2023/5
Y1 - 2023/5
N2 - Organic electrode materials are considered as ideal candidates for the next generation of rechargeable batteries owing to their safety, environmental friendliness, sustainability, structure designability, and low price. Among them, organosulfur compounds are promising cathodes for advanced lithium batteries due to their high theoretical capacity and working potential, and have attracted much attention. However, some intrinsic problems such as low conductivity, high solubility in electrolytes, and poor stability have seriously affected the promising perspective of organosulfur cathode materials. This review introduces the latest researches on the basic properties and reaction mechanisms of organosulfur compounds (thioether, organodisulfide, organopolysulfide, and sulfurized polyacrylonitrile) and summarizes the design strategies to improve their capacity, voltage plateau, cycling stability, and rate performance caused by intrinsic problems. In this review, significant challenges and prospects of organosulfur compounds as cathode materials of lithium batteries are investigated. The purpose of this review is to provide meaningful guidance for researchers to promote the development of organosulfur cathode materials.
AB - Organic electrode materials are considered as ideal candidates for the next generation of rechargeable batteries owing to their safety, environmental friendliness, sustainability, structure designability, and low price. Among them, organosulfur compounds are promising cathodes for advanced lithium batteries due to their high theoretical capacity and working potential, and have attracted much attention. However, some intrinsic problems such as low conductivity, high solubility in electrolytes, and poor stability have seriously affected the promising perspective of organosulfur cathode materials. This review introduces the latest researches on the basic properties and reaction mechanisms of organosulfur compounds (thioether, organodisulfide, organopolysulfide, and sulfurized polyacrylonitrile) and summarizes the design strategies to improve their capacity, voltage plateau, cycling stability, and rate performance caused by intrinsic problems. In this review, significant challenges and prospects of organosulfur compounds as cathode materials of lithium batteries are investigated. The purpose of this review is to provide meaningful guidance for researchers to promote the development of organosulfur cathode materials.
KW - cathode
KW - cycling peformance
KW - high energy denisty
KW - lithium battery
KW - organosulfur
UR - http://www.scopus.com/inward/record.url?scp=85149845260&partnerID=8YFLogxK
U2 - 10.1016/j.mattod.2023.02.027
DO - 10.1016/j.mattod.2023.02.027
M3 - 文献综述
AN - SCOPUS:85149845260
SN - 1369-7021
VL - 65
SP - 100
EP - 121
JO - Materials Today
JF - Materials Today
ER -