Self-assembly of 3-D 4d-4f coordination frameworks based on pyridine-3,5-dicarboxylic acid: Syntheses, crystal structures and luminescence

Guang Xiang Liu; Yu Yong Xu; Xiao Ming Ren; Sadafumi Nishihara; Rong Yi Huang

doi:10.1016/j.ica.2010.05.026

Self-assembly of 3-D 4d-4f coordination frameworks based on pyridine-3,5-dicarboxylic acid: Syntheses, crystal structures and luminescence

Guang Xiang Liu, Yu Yong Xu, Xiao Ming Ren, Sadafumi Nishihara, Rong Yi Huang

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

The hydrothermal reactions of H₂PDC, AgNO₃ with Eu₂O₃ or Tb(NO₃)₃·6H ₂O gave rise to two novel three-dimensional 4d-4f heterometallic metal-organic coordination polymers, AgEu(PDC)₂ (1) and AgTb(PDC)₂ (2) (H₂PDC = pyridine-3,5-dicarboxylic acid), and characterized by elemental analysis, IR, thermal analysis and single-crystal X-ray diffraction. Complexes 1 and 2 crystallize in the monoclinic system, P2/c space group; the structure determination reveal that both of them are isostructural and feature an unusual three-dimensional heterometallic network structure in which infinite lanthanide-carboxylate chains are linked by [Ag(PDC)₂]^3- metalloligands to form a mixed-metal coordination network. Moreover, the luminescent properties of two complexes have also been investigated at room temperature.

Original language	English
Pages (from-to)	3727-3732
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	363
Issue number	14
DOIs	https://doi.org/10.1016/j.ica.2010.05.026
State	Published - 25 Nov 2010
Externally published	Yes

Keywords

Crystal structure
Heterometallic coordination polymer
Luminescence

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title = "Self-assembly of 3-D 4d-4f coordination frameworks based on pyridine-3,5-dicarboxylic acid: Syntheses, crystal structures and luminescence",

abstract = "The hydrothermal reactions of H2PDC, AgNO3 with Eu2O3 or Tb(NO3)3·6H 2O gave rise to two novel three-dimensional 4d-4f heterometallic metal-organic coordination polymers, AgEu(PDC)2 (1) and AgTb(PDC)2 (2) (H2PDC = pyridine-3,5-dicarboxylic acid), and characterized by elemental analysis, IR, thermal analysis and single-crystal X-ray diffraction. Complexes 1 and 2 crystallize in the monoclinic system, P2/c space group; the structure determination reveal that both of them are isostructural and feature an unusual three-dimensional heterometallic network structure in which infinite lanthanide-carboxylate chains are linked by [Ag(PDC)2]3- metalloligands to form a mixed-metal coordination network. Moreover, the luminescent properties of two complexes have also been investigated at room temperature.",

keywords = "Crystal structure, Heterometallic coordination polymer, Luminescence",

author = "Liu, {Guang Xiang} and Xu, {Yu Yong} and Ren, {Xiao Ming} and Sadafumi Nishihara and Huang, {Rong Yi}",

year = "2010",

month = nov,

day = "25",

doi = "10.1016/j.ica.2010.05.026",

language = "英语",

volume = "363",

pages = "3727--3732",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

number = "14",

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TY - JOUR

T1 - Self-assembly of 3-D 4d-4f coordination frameworks based on pyridine-3,5-dicarboxylic acid

T2 - Syntheses, crystal structures and luminescence

AU - Liu, Guang Xiang

AU - Xu, Yu Yong

AU - Ren, Xiao Ming

AU - Nishihara, Sadafumi

AU - Huang, Rong Yi

PY - 2010/11/25

Y1 - 2010/11/25

N2 - The hydrothermal reactions of H2PDC, AgNO3 with Eu2O3 or Tb(NO3)3·6H 2O gave rise to two novel three-dimensional 4d-4f heterometallic metal-organic coordination polymers, AgEu(PDC)2 (1) and AgTb(PDC)2 (2) (H2PDC = pyridine-3,5-dicarboxylic acid), and characterized by elemental analysis, IR, thermal analysis and single-crystal X-ray diffraction. Complexes 1 and 2 crystallize in the monoclinic system, P2/c space group; the structure determination reveal that both of them are isostructural and feature an unusual three-dimensional heterometallic network structure in which infinite lanthanide-carboxylate chains are linked by [Ag(PDC)2]3- metalloligands to form a mixed-metal coordination network. Moreover, the luminescent properties of two complexes have also been investigated at room temperature.

AB - The hydrothermal reactions of H2PDC, AgNO3 with Eu2O3 or Tb(NO3)3·6H 2O gave rise to two novel three-dimensional 4d-4f heterometallic metal-organic coordination polymers, AgEu(PDC)2 (1) and AgTb(PDC)2 (2) (H2PDC = pyridine-3,5-dicarboxylic acid), and characterized by elemental analysis, IR, thermal analysis and single-crystal X-ray diffraction. Complexes 1 and 2 crystallize in the monoclinic system, P2/c space group; the structure determination reveal that both of them are isostructural and feature an unusual three-dimensional heterometallic network structure in which infinite lanthanide-carboxylate chains are linked by [Ag(PDC)2]3- metalloligands to form a mixed-metal coordination network. Moreover, the luminescent properties of two complexes have also been investigated at room temperature.

KW - Crystal structure

KW - Heterometallic coordination polymer

KW - Luminescence

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U2 - 10.1016/j.ica.2010.05.026

DO - 10.1016/j.ica.2010.05.026

M3 - 文章

AN - SCOPUS:77957976780

SN - 0020-1693

VL - 363

SP - 3727

EP - 3732

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 14

ER -

Self-assembly of 3-D 4d-4f coordination frameworks based on pyridine-3,5-dicarboxylic acid: Syntheses, crystal structures and luminescence

Abstract

Keywords

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