Se2NCl3 and [Se2NCl2]+ [GaCl4]−, Chloride Nitrides of Trivalent Selenium

René Wollert; Antje Höllwarth; Gernot Frenking; Dieter Fenske; Helmut Goesmann; Kurt Dehnicke

doi:10.1002/anie.199212511

Se₂NCl₃ and [Se₂NCl₂]⁺ [GaCl₄]⁻, Chloride Nitrides of Trivalent Selenium

René Wollert, Antje Höllwarth, Gernot Frenking, Dieter Fenske, Helmut Goesmann, Kurt Dehnicke

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The planar structure with C_2v symmetry resembles a compass in the case of Se₂NCl₃ (1), a chlorine nitride, which is readily soluble and stable, but at the same time very reactive. The chlorine atom in 1 bridging the selenium atoms can be readily removed with GaCl₃ to form [Se₂NCl₂][GaCl₄] in which the cation is U‐shaped. Both compounds have a diamagnetic singlet ground state. (Figure Presented.)

Original language	English
Pages (from-to)	1251-1253
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	31
Issue number	9
DOIs	https://doi.org/10.1002/anie.199212511
State	Published - Sep 1992
Externally published	Yes

Access to Document

10.1002/anie.199212511

Cite this

@article{8680fc7aa10442afbd988d80c8bfa810,

title = "Se2NCl3 and [Se2NCl2]+ [GaCl4]−, Chloride Nitrides of Trivalent Selenium",

abstract = "The planar structure with C2v symmetry resembles a compass in the case of Se2NCl3 (1), a chlorine nitride, which is readily soluble and stable, but at the same time very reactive. The chlorine atom in 1 bridging the selenium atoms can be readily removed with GaCl3 to form [Se2NCl2][GaCl4] in which the cation is U‐shaped. Both compounds have a diamagnetic singlet ground state. (Figure Presented.)",

author = "Ren{\'e} Wollert and Antje H{\"o}llwarth and Gernot Frenking and Dieter Fenske and Helmut Goesmann and Kurt Dehnicke",

year = "1992",

month = sep,

doi = "10.1002/anie.199212511",

language = "英语",

volume = "31",

pages = "1251--1253",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "9",

}

TY - JOUR

T1 - Se2NCl3 and [Se2NCl2]+ [GaCl4]−, Chloride Nitrides of Trivalent Selenium

AU - Wollert, René

AU - Höllwarth, Antje

AU - Frenking, Gernot

AU - Fenske, Dieter

AU - Goesmann, Helmut

AU - Dehnicke, Kurt

PY - 1992/9

Y1 - 1992/9

N2 - The planar structure with C2v symmetry resembles a compass in the case of Se2NCl3 (1), a chlorine nitride, which is readily soluble and stable, but at the same time very reactive. The chlorine atom in 1 bridging the selenium atoms can be readily removed with GaCl3 to form [Se2NCl2][GaCl4] in which the cation is U‐shaped. Both compounds have a diamagnetic singlet ground state. (Figure Presented.)

AB - The planar structure with C2v symmetry resembles a compass in the case of Se2NCl3 (1), a chlorine nitride, which is readily soluble and stable, but at the same time very reactive. The chlorine atom in 1 bridging the selenium atoms can be readily removed with GaCl3 to form [Se2NCl2][GaCl4] in which the cation is U‐shaped. Both compounds have a diamagnetic singlet ground state. (Figure Presented.)

UR - http://www.scopus.com/inward/record.url?scp=33748214272&partnerID=8YFLogxK

U2 - 10.1002/anie.199212511

DO - 10.1002/anie.199212511

M3 - 文章

AN - SCOPUS:33748214272

SN - 1433-7851

VL - 31

SP - 1251

EP - 1253

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 9

ER -

Se₂NCl₃ and [Se₂NCl₂]⁺ [GaCl₄]⁻, Chloride Nitrides of Trivalent Selenium

Abstract

Access to Document

Other files and links

Fingerprint

Cite this