S(NPMe3) 42+: The First Structure Determination of a Dication of Hexavalent Sulfur

Hella Folkerts; Wolfgang Hiller; Martin Herker; Sergei F. Vyboishchikov; Gernot Frenking; Kurt Dehnicke

doi:10.1002/anie.199513621

S(NPMe₃) 42+: The First Structure Determination of a Dication of Hexavalent Sulfur

Hella Folkerts, Wolfgang Hiller, Martin Herker, Sergei F. Vyboishchikov, Gernot Frenking, Kurt Dehnicke

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Attraction of the charges on the participant atoms causes the polar covalent NS and NP single bonds in the cation of the phosphorane iminato complex [S(NPMe₃)₄]Cl₂ (shown on the right) to approach the lengths of double bonds. This is in agreement with the results of ab initio calculations. The complex was obtained from S₂Cl₂ and the silylated phosphorane imine Me₃SiNPMe₃ in acetonitrile. (Figure Presented.)

Original language	English
Pages (from-to)	1362-1363
Number of pages	2
Journal	Angewandte Chemie - International Edition
Volume	34
Issue number	12
DOIs	https://doi.org/10.1002/anie.199513621
State	Published - 7 Jul 1995
Externally published	Yes

Keywords

ab initio calculations
imines
phosphorus compounds
sulfur compounds

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title = "S(NPMe3) 42+: The First Structure Determination of a Dication of Hexavalent Sulfur",

abstract = "Attraction of the charges on the participant atoms causes the polar covalent NS and NP single bonds in the cation of the phosphorane iminato complex [S(NPMe3)4]Cl2 (shown on the right) to approach the lengths of double bonds. This is in agreement with the results of ab initio calculations. The complex was obtained from S2Cl2 and the silylated phosphorane imine Me3SiNPMe3 in acetonitrile. (Figure Presented.)",

keywords = "ab initio calculations, imines, phosphorus compounds, sulfur compounds",

author = "Hella Folkerts and Wolfgang Hiller and Martin Herker and Vyboishchikov, {Sergei F.} and Gernot Frenking and Kurt Dehnicke",

year = "1995",

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T2 - The First Structure Determination of a Dication of Hexavalent Sulfur

AU - Folkerts, Hella

AU - Hiller, Wolfgang

AU - Herker, Martin

AU - Vyboishchikov, Sergei F.

AU - Frenking, Gernot

AU - Dehnicke, Kurt

PY - 1995/7/7

Y1 - 1995/7/7

N2 - Attraction of the charges on the participant atoms causes the polar covalent NS and NP single bonds in the cation of the phosphorane iminato complex [S(NPMe3)4]Cl2 (shown on the right) to approach the lengths of double bonds. This is in agreement with the results of ab initio calculations. The complex was obtained from S2Cl2 and the silylated phosphorane imine Me3SiNPMe3 in acetonitrile. (Figure Presented.)

AB - Attraction of the charges on the participant atoms causes the polar covalent NS and NP single bonds in the cation of the phosphorane iminato complex [S(NPMe3)4]Cl2 (shown on the right) to approach the lengths of double bonds. This is in agreement with the results of ab initio calculations. The complex was obtained from S2Cl2 and the silylated phosphorane imine Me3SiNPMe3 in acetonitrile. (Figure Presented.)

KW - ab initio calculations

KW - imines

KW - phosphorus compounds

KW - sulfur compounds

UR - http://www.scopus.com/inward/record.url?scp=33751145706&partnerID=8YFLogxK

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DO - 10.1002/anie.199513621

M3 - 文章

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 12

ER -

S(NPMe₃) 42+: The First Structure Determination of a Dication of Hexavalent Sulfur

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