Solvothermal synthesis, crystal structure and luminescence of the first organic amine templated europium sulfate

Yalin Zhu; Xiaochang Sun; Dunru Zhu; Yan Xu

doi:10.1016/j.ica.2008.11.015

Solvothermal synthesis, crystal structure and luminescence of the first organic amine templated europium sulfate

Yalin Zhu, Xiaochang Sun, Dunru Zhu, Yan Xu

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

The first organic amine templated europium sulfate [C₂N₂H₁₀]_1.5[Eu(SO₄)₃(H₂O)] · 2H₂O (1), has been synthesized under solvothermal conditions by using a mixture of n-butanol and water as the solvent. The colorless block crystals were characterized by IR, TGA and ICP. Crystal structure analysis shows that the corrugated layered framework of compound 1 is constructed from EuO₉ polyhedra and sulfate groups, while non-coordination water molecules and ethylenediamine molecules link the adjacent layers by hydrogen bonds. Compound 1 represents a strong luminescence upon the excitation.

Original language	English
Pages (from-to)	2565-2568
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	362
Issue number	8
DOIs	https://doi.org/10.1016/j.ica.2008.11.015
State	Published - 1 Jun 2009

Keywords

Crystal structure
Europium sulfate
Luminescence
Solvothermal synthesis

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title = "Solvothermal synthesis, crystal structure and luminescence of the first organic amine templated europium sulfate",

abstract = "The first organic amine templated europium sulfate [C2N2H10]1.5[Eu(SO4)3(H2O)] · 2H2O (1), has been synthesized under solvothermal conditions by using a mixture of n-butanol and water as the solvent. The colorless block crystals were characterized by IR, TGA and ICP. Crystal structure analysis shows that the corrugated layered framework of compound 1 is constructed from EuO9 polyhedra and sulfate groups, while non-coordination water molecules and ethylenediamine molecules link the adjacent layers by hydrogen bonds. Compound 1 represents a strong luminescence upon the excitation.",

keywords = "Crystal structure, Europium sulfate, Luminescence, Solvothermal synthesis",

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T1 - Solvothermal synthesis, crystal structure and luminescence of the first organic amine templated europium sulfate

AU - Zhu, Yalin

AU - Sun, Xiaochang

AU - Zhu, Dunru

AU - Xu, Yan

PY - 2009/6/1

Y1 - 2009/6/1

N2 - The first organic amine templated europium sulfate [C2N2H10]1.5[Eu(SO4)3(H2O)] · 2H2O (1), has been synthesized under solvothermal conditions by using a mixture of n-butanol and water as the solvent. The colorless block crystals were characterized by IR, TGA and ICP. Crystal structure analysis shows that the corrugated layered framework of compound 1 is constructed from EuO9 polyhedra and sulfate groups, while non-coordination water molecules and ethylenediamine molecules link the adjacent layers by hydrogen bonds. Compound 1 represents a strong luminescence upon the excitation.

AB - The first organic amine templated europium sulfate [C2N2H10]1.5[Eu(SO4)3(H2O)] · 2H2O (1), has been synthesized under solvothermal conditions by using a mixture of n-butanol and water as the solvent. The colorless block crystals were characterized by IR, TGA and ICP. Crystal structure analysis shows that the corrugated layered framework of compound 1 is constructed from EuO9 polyhedra and sulfate groups, while non-coordination water molecules and ethylenediamine molecules link the adjacent layers by hydrogen bonds. Compound 1 represents a strong luminescence upon the excitation.

KW - Crystal structure

KW - Europium sulfate

KW - Luminescence

KW - Solvothermal synthesis

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DO - 10.1016/j.ica.2008.11.015

M3 - 文章

AN - SCOPUS:64949108083

SN - 0020-1693

VL - 362

SP - 2565

EP - 2568

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 8

ER -

Solvothermal synthesis, crystal structure and luminescence of the first organic amine templated europium sulfate

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Keywords

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