TY - JOUR
T1 - Solvothermal synthesis, crystal structure and properties of a new organic templated lanthanum sulfate [C4N3H16] [La(SO4)3(H2O)]
AU - Zhu, Yalin
AU - Zhou, Guangpeng
AU - Xu, Yan
AU - Zhu, Dunru
AU - Zheng, Xuefang
PY - 2008/3
Y1 - 2008/3
N2 - A new organic templated lanthanum sulfate [C4N3H 16][La(SO4)3(H2O)] (1) has been solvothermally synthesized by using n-butanol as solvent. The colorless block crystals were characterized by IR, TGA, ICP, and XRD. The structure was determined by single-crystal X-ray diffraction: Monoclinic, P21/c, a = 10.8878(19), b = 15.478(3), c = 9.9639(18)Å, β = 114.062(2)°, V=1533.2(5) Å 3, Z = 4]. Crystal structure analysis shows that the one dimensional chain of 1 consists of the LaO9 polyhedra and the sulfate groups. Coordination water molecules link adjacent chains by using hydrogen bonds to generate 2D layers, whereas the organic amines are inserted between the layers. The formation of 1 demonstrates that solvents play an important role during the synthesis.
AB - A new organic templated lanthanum sulfate [C4N3H 16][La(SO4)3(H2O)] (1) has been solvothermally synthesized by using n-butanol as solvent. The colorless block crystals were characterized by IR, TGA, ICP, and XRD. The structure was determined by single-crystal X-ray diffraction: Monoclinic, P21/c, a = 10.8878(19), b = 15.478(3), c = 9.9639(18)Å, β = 114.062(2)°, V=1533.2(5) Å 3, Z = 4]. Crystal structure analysis shows that the one dimensional chain of 1 consists of the LaO9 polyhedra and the sulfate groups. Coordination water molecules link adjacent chains by using hydrogen bonds to generate 2D layers, whereas the organic amines are inserted between the layers. The formation of 1 demonstrates that solvents play an important role during the synthesis.
KW - Crystal structure
KW - Lanthanum
KW - Solvothermal synthesis
KW - Sulfate
UR - http://www.scopus.com/inward/record.url?scp=53849129904&partnerID=8YFLogxK
U2 - 10.1002/zaac.200700455
DO - 10.1002/zaac.200700455
M3 - 文章
AN - SCOPUS:53849129904
SN - 0044-2313
VL - 634
SP - 545
EP - 548
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
IS - 3
ER -