TY - JOUR
T1 - Studies of equilibrium, kinetics simulation and thermodynamics of cAMP adsorption onto an anion-exchange resin
AU - Qian, Wenbin
AU - Lin, Xiaoqing
AU - Zhou, Xiqun
AU - Chen, Xiaochun
AU - Xiong, Jian
AU - Bai, Jianxin
AU - Ying, Hanjie
PY - 2010/12/15
Y1 - 2010/12/15
N2 - In a batch equilibrium system, the maximum adsorption capacity of cAMP onto an anion-exchange resin reached 0.1718, 0.1956, 0.2764 and 0.3437gg-1 at 283, 293, 303 and 313K, respectively. The adsorption data obtained were well described by the Langmuir isotherm. In the batch kinetic system, Fick diffusion, pseudo first-order and pseudo second-order models were applied to simulate the experimental kinetic data. The results revealed that the Fick model best described the adsorption process, and clearly predicted the intraparticle distribution of the concentration. The effective diffusion coefficients (De) for 283, 293, 303 and 313K were 0.37×10-10, 0.51×10-10, 0.86×10-10 and 1.41×10-10m2s-1, respectively. The thermodynamic parameters such as ΔG0, which were all negative, indicated that the adsorption of cAMP onto the anion-exchange resin was spontaneous and the positive value of ΔH0 (+8.66kJmol-1) showed that the adsorption was an endothermic reaction.
AB - In a batch equilibrium system, the maximum adsorption capacity of cAMP onto an anion-exchange resin reached 0.1718, 0.1956, 0.2764 and 0.3437gg-1 at 283, 293, 303 and 313K, respectively. The adsorption data obtained were well described by the Langmuir isotherm. In the batch kinetic system, Fick diffusion, pseudo first-order and pseudo second-order models were applied to simulate the experimental kinetic data. The results revealed that the Fick model best described the adsorption process, and clearly predicted the intraparticle distribution of the concentration. The effective diffusion coefficients (De) for 283, 293, 303 and 313K were 0.37×10-10, 0.51×10-10, 0.86×10-10 and 1.41×10-10m2s-1, respectively. The thermodynamic parameters such as ΔG0, which were all negative, indicated that the adsorption of cAMP onto the anion-exchange resin was spontaneous and the positive value of ΔH0 (+8.66kJmol-1) showed that the adsorption was an endothermic reaction.
KW - Adsorption
KW - CAMP
KW - Effective diffusion coefficient
KW - Fick model
KW - Langmuir
UR - http://www.scopus.com/inward/record.url?scp=78649450379&partnerID=8YFLogxK
U2 - 10.1016/j.cej.2010.09.073
DO - 10.1016/j.cej.2010.09.073
M3 - 文章
AN - SCOPUS:78649450379
SN - 1385-8947
VL - 165
SP - 907
EP - 915
JO - Chemical Engineering Journal
JF - Chemical Engineering Journal
IS - 3
ER -