Study on properties and synthesis of polymer schiff base with ferrocene and bi-thiazole

Guo Xuan Xiong; Dong Hai Zeng; Yu Fen Zhou; Chun Hua Lu

Study on properties and synthesis of polymer schiff base with ferrocene and bi-thiazole

Guo Xuan Xiong, Dong Hai Zeng, Yu Fen Zhou, Chun Hua Lu

College of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

The DABT was synthesized with 2, 3-butanedione, liquid dibromine, and thiourea and the ferrocenyl schiff base was synthesized by DABT and ferrocenecarboxaldehyde. Then polymer of ferrocenyl schiff base was prepared by the Friedel-Crafts method, their metal complexes were made by doping Fe²⁺, Ni²⁺ and Cu²⁺sulfates. Their structures were characterized by infrared spectra and ¹H-NMR spectra, conductivity and magnetism properties were measured with a Four-point probe Instrument and gouy magnetic balance. The experiment results showed that the synthetical product was polymer of ferrocenyl schiff base, its conductivity was 1.61×10^-6 S·cm^-1 belonging to semiconductor. Magnetism properties of metal complexes by doping Fe²⁺, Ni²⁺ and Cu²+ sulfates were obviously higher than polymer of un-doping, and properties of complexes by doping Cu²⁺sulfate was best. These properties indicated they can be applied as a new organic functional electromagnetism material.

Original language	English
Pages (from-to)	1-4
Number of pages	4
Journal	Cailiao Gongcheng/Journal of Materials Engineering
Issue number	11
State	Published - Nov 2008

Keywords

Bi-thiazole
Ferrocene
Property
Schiff base
Synthesis

Cite this

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title = "Study on properties and synthesis of polymer schiff base with ferrocene and bi-thiazole",

abstract = "The DABT was synthesized with 2, 3-butanedione, liquid dibromine, and thiourea and the ferrocenyl schiff base was synthesized by DABT and ferrocenecarboxaldehyde. Then polymer of ferrocenyl schiff base was prepared by the Friedel-Crafts method, their metal complexes were made by doping Fe2+, Ni2+ and Cu2+sulfates. Their structures were characterized by infrared spectra and 1H-NMR spectra, conductivity and magnetism properties were measured with a Four-point probe Instrument and gouy magnetic balance. The experiment results showed that the synthetical product was polymer of ferrocenyl schiff base, its conductivity was 1.61×10-6 S·cm-1 belonging to semiconductor. Magnetism properties of metal complexes by doping Fe2+, Ni2+ and Cu2+ sulfates were obviously higher than polymer of un-doping, and properties of complexes by doping Cu2+sulfate was best. These properties indicated they can be applied as a new organic functional electromagnetism material.",

keywords = "Bi-thiazole, Ferrocene, Property, Schiff base, Synthesis",

author = "Xiong, {Guo Xuan} and Zeng, {Dong Hai} and Zhou, {Yu Fen} and Lu, {Chun Hua}",

year = "2008",

month = nov,

language = "英语",

pages = "1--4",

journal = "Cailiao Gongcheng/Journal of Materials Engineering",

issn = "1001-4381",

publisher = "Science China Press",

number = "11",

}

TY - JOUR

T1 - Study on properties and synthesis of polymer schiff base with ferrocene and bi-thiazole

AU - Xiong, Guo Xuan

AU - Zeng, Dong Hai

AU - Zhou, Yu Fen

AU - Lu, Chun Hua

PY - 2008/11

Y1 - 2008/11

N2 - The DABT was synthesized with 2, 3-butanedione, liquid dibromine, and thiourea and the ferrocenyl schiff base was synthesized by DABT and ferrocenecarboxaldehyde. Then polymer of ferrocenyl schiff base was prepared by the Friedel-Crafts method, their metal complexes were made by doping Fe2+, Ni2+ and Cu2+sulfates. Their structures were characterized by infrared spectra and 1H-NMR spectra, conductivity and magnetism properties were measured with a Four-point probe Instrument and gouy magnetic balance. The experiment results showed that the synthetical product was polymer of ferrocenyl schiff base, its conductivity was 1.61×10-6 S·cm-1 belonging to semiconductor. Magnetism properties of metal complexes by doping Fe2+, Ni2+ and Cu2+ sulfates were obviously higher than polymer of un-doping, and properties of complexes by doping Cu2+sulfate was best. These properties indicated they can be applied as a new organic functional electromagnetism material.

AB - The DABT was synthesized with 2, 3-butanedione, liquid dibromine, and thiourea and the ferrocenyl schiff base was synthesized by DABT and ferrocenecarboxaldehyde. Then polymer of ferrocenyl schiff base was prepared by the Friedel-Crafts method, their metal complexes were made by doping Fe2+, Ni2+ and Cu2+sulfates. Their structures were characterized by infrared spectra and 1H-NMR spectra, conductivity and magnetism properties were measured with a Four-point probe Instrument and gouy magnetic balance. The experiment results showed that the synthetical product was polymer of ferrocenyl schiff base, its conductivity was 1.61×10-6 S·cm-1 belonging to semiconductor. Magnetism properties of metal complexes by doping Fe2+, Ni2+ and Cu2+ sulfates were obviously higher than polymer of un-doping, and properties of complexes by doping Cu2+sulfate was best. These properties indicated they can be applied as a new organic functional electromagnetism material.

KW - Bi-thiazole

KW - Ferrocene

KW - Property

KW - Schiff base

KW - Synthesis

UR - http://www.scopus.com/inward/record.url?scp=58249094391&partnerID=8YFLogxK

M3 - 文章

AN - SCOPUS:58249094391

SN - 1001-4381

SP - 1

EP - 4

JO - Cailiao Gongcheng/Journal of Materials Engineering

JF - Cailiao Gongcheng/Journal of Materials Engineering

IS - 11

ER -

Study on properties and synthesis of polymer schiff base with ferrocene and bi-thiazole

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Keywords

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