Sulfated copper oxide: An efficient catalyst for dehydration of sorbitol to isosorbide

Jiaojiao Xia; Dinghua Yu; Yi Hu; Bin Zou; Peng Sun; Heng Li; He Huang

doi:10.1016/j.catcom.2010.12.002

Sulfated copper oxide: An efficient catalyst for dehydration of sorbitol to isosorbide

Jiaojiao Xia, Dinghua Yu, Yi Hu, Bin Zou, Peng Sun, Heng Li, He Huang

School of Pharmaceutical Sciences

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

87 Scopus citations

Abstract

Sulfated metal oxides catalysts prepared by calcining hydrated metal sulfates were studied for sorbitol dehydration to isosorbide. The selectivity to isosorbide was obviously affected by the calcination temperature. Sulfated copper oxide calcined at 650 °C exhibited the best catalytic performance, 99.7% sorbitol conversion and 67.5% isosorbide selectivity were gained at the reaction temperature of 200 °C. Characterizations with N₂ adsorption, XRD, NH₃-TPD, UV-vis and FT-IR revealed that calcination temperature influenced the catalytic behaviors dramatically by changing the crystalline structure and surface properties.

Original language	English
Pages (from-to)	544-547
Number of pages	4
Journal	Catalysis Communications
Volume	12
Issue number	6
DOIs	https://doi.org/10.1016/j.catcom.2010.12.002
State	Published - 10 Feb 2011

Keywords

Dehydration
Isosorbide
Sorbitol
Sulfated copper oxide

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10.1016/j.catcom.2010.12.002

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title = "Sulfated copper oxide: An efficient catalyst for dehydration of sorbitol to isosorbide",

abstract = "Sulfated metal oxides catalysts prepared by calcining hydrated metal sulfates were studied for sorbitol dehydration to isosorbide. The selectivity to isosorbide was obviously affected by the calcination temperature. Sulfated copper oxide calcined at 650 °C exhibited the best catalytic performance, 99.7% sorbitol conversion and 67.5% isosorbide selectivity were gained at the reaction temperature of 200 °C. Characterizations with N2 adsorption, XRD, NH3-TPD, UV-vis and FT-IR revealed that calcination temperature influenced the catalytic behaviors dramatically by changing the crystalline structure and surface properties.",

keywords = "Dehydration, Isosorbide, Sorbitol, Sulfated copper oxide",

author = "Jiaojiao Xia and Dinghua Yu and Yi Hu and Bin Zou and Peng Sun and Heng Li and He Huang",

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doi = "10.1016/j.catcom.2010.12.002",

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T2 - An efficient catalyst for dehydration of sorbitol to isosorbide

AU - Xia, Jiaojiao

AU - Yu, Dinghua

AU - Hu, Yi

AU - Zou, Bin

AU - Sun, Peng

AU - Li, Heng

AU - Huang, He

PY - 2011/2/10

Y1 - 2011/2/10

N2 - Sulfated metal oxides catalysts prepared by calcining hydrated metal sulfates were studied for sorbitol dehydration to isosorbide. The selectivity to isosorbide was obviously affected by the calcination temperature. Sulfated copper oxide calcined at 650 °C exhibited the best catalytic performance, 99.7% sorbitol conversion and 67.5% isosorbide selectivity were gained at the reaction temperature of 200 °C. Characterizations with N2 adsorption, XRD, NH3-TPD, UV-vis and FT-IR revealed that calcination temperature influenced the catalytic behaviors dramatically by changing the crystalline structure and surface properties.

AB - Sulfated metal oxides catalysts prepared by calcining hydrated metal sulfates were studied for sorbitol dehydration to isosorbide. The selectivity to isosorbide was obviously affected by the calcination temperature. Sulfated copper oxide calcined at 650 °C exhibited the best catalytic performance, 99.7% sorbitol conversion and 67.5% isosorbide selectivity were gained at the reaction temperature of 200 °C. Characterizations with N2 adsorption, XRD, NH3-TPD, UV-vis and FT-IR revealed that calcination temperature influenced the catalytic behaviors dramatically by changing the crystalline structure and surface properties.

KW - Dehydration

KW - Isosorbide

KW - Sorbitol

KW - Sulfated copper oxide

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DO - 10.1016/j.catcom.2010.12.002

M3 - 文章

AN - SCOPUS:78650587334

SN - 1566-7367

VL - 12

SP - 544

EP - 547

JO - Catalysis Communications

JF - Catalysis Communications

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ER -

Sulfated copper oxide: An efficient catalyst for dehydration of sorbitol to isosorbide

Abstract

Keywords

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