Syntheses, structures and magnetic properties of two unprecedented hybrid compounds constructed from open Wells-Dawson anions and high-nuclear transition metal clusters

Jiuyu Guo; Deng Zhang; Lei Chen; You Song; Dunru Zhu; Yan Xu

doi:10.1039/c3dt50155h

Syntheses, structures and magnetic properties of two unprecedented hybrid compounds constructed from open Wells-Dawson anions and high-nuclear transition metal clusters

Jiuyu Guo, Deng Zhang, Lei Chen, You Song, Dunru Zhu, Yan Xu

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Two new inorganic-organic hybrid compounds Na₂(C ₃N₂H₁₂)₄{[Ni₅(OH) ₃(H₂O)₄(CH₃CO₂)][Si ₂W₁₈O₆₆]}·12.5H₂O (1) and (C₃N₂H₁₂)₃{[Co^II ₂Co^III₄(OH)₅(H₂O) ₂(CH₃CO₂)][Si₂W₁₈O ₆₆]}·6H₂O·(C₃N₂H ₁₀) (2), based on lacunary polyoxometalates and high-nuclear transition-metal clusters, have been synthesized by a new method (solvothermal method). Single crystal XRD, magnetic measurements, nonlinear-optical (NLO) measurements, thermogravimetric (TG) measurements, and IR spectra were performed to analyze the structures and properties of 1 and 2. XRD analyses reveal that compound 1 consists of an open Wells-Dawson anion [Si₂W ₁₈O₆₆]^16-, a five-nuclear cationic cluster [Ni₅(OH)₃(H₂O)₄(CH ₃CO₂)]⁶⁺, free Na⁺ cations, and protonated 1,3-diaminopropanes. Compound 2 has a similar structure to 1, while a six-nuclear cationic cluster [Co^II₂Co^III ₄(OH)₅(H₂O)₂(CH₃CO ₂)]¹⁰⁺ replaces the five-nuclear cationic cluster [Ni ₅(OH)₃(H₂O)₄(CH₃CO ₂)]⁶⁺ in 1. Magnetic susceptibility measurements indicate antiferromagnetic interactions in 1, and the chirality of compound 2 may bring potential properties of catalysis and optical nonlinearity.

Original language	English
Pages (from-to)	8454-8459
Number of pages	6
Journal	Dalton Transactions
Volume	42
Issue number	23
DOIs	https://doi.org/10.1039/c3dt50155h
State	Published - 21 Jun 2013

Access to Document

10.1039/c3dt50155h

Cite this

@article{efe9cc5f2529426d96681011d46bf84e,

title = "Syntheses, structures and magnetic properties of two unprecedented hybrid compounds constructed from open Wells-Dawson anions and high-nuclear transition metal clusters",

abstract = "Two new inorganic-organic hybrid compounds Na2(C 3N2H12)4{[Ni5(OH) 3(H2O)4(CH3CO2)][Si 2W18O66]}·12.5H2O (1) and (C3N2H12)3{[CoII 2CoIII4(OH)5(H2O) 2(CH3CO2)][Si2W18O 66]}·6H2O·(C3N2H 10) (2), based on lacunary polyoxometalates and high-nuclear transition-metal clusters, have been synthesized by a new method (solvothermal method). Single crystal XRD, magnetic measurements, nonlinear-optical (NLO) measurements, thermogravimetric (TG) measurements, and IR spectra were performed to analyze the structures and properties of 1 and 2. XRD analyses reveal that compound 1 consists of an open Wells-Dawson anion [Si2W 18O66]16-, a five-nuclear cationic cluster [Ni5(OH)3(H2O)4(CH 3CO2)]6+, free Na+ cations, and protonated 1,3-diaminopropanes. Compound 2 has a similar structure to 1, while a six-nuclear cationic cluster [CoII2CoIII 4(OH)5(H2O)2(CH3CO 2)]10+ replaces the five-nuclear cationic cluster [Ni 5(OH)3(H2O)4(CH3CO 2)]6+ in 1. Magnetic susceptibility measurements indicate antiferromagnetic interactions in 1, and the chirality of compound 2 may bring potential properties of catalysis and optical nonlinearity.",

author = "Jiuyu Guo and Deng Zhang and Lei Chen and You Song and Dunru Zhu and Yan Xu",

year = "2013",

month = jun,

day = "21",

doi = "10.1039/c3dt50155h",

language = "英语",

volume = "42",

pages = "8454--8459",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "23",

}

TY - JOUR

T1 - Syntheses, structures and magnetic properties of two unprecedented hybrid compounds constructed from open Wells-Dawson anions and high-nuclear transition metal clusters

AU - Guo, Jiuyu

AU - Zhang, Deng

AU - Chen, Lei

AU - Song, You

AU - Zhu, Dunru

AU - Xu, Yan

PY - 2013/6/21

Y1 - 2013/6/21

N2 - Two new inorganic-organic hybrid compounds Na2(C 3N2H12)4{[Ni5(OH) 3(H2O)4(CH3CO2)][Si 2W18O66]}·12.5H2O (1) and (C3N2H12)3{[CoII 2CoIII4(OH)5(H2O) 2(CH3CO2)][Si2W18O 66]}·6H2O·(C3N2H 10) (2), based on lacunary polyoxometalates and high-nuclear transition-metal clusters, have been synthesized by a new method (solvothermal method). Single crystal XRD, magnetic measurements, nonlinear-optical (NLO) measurements, thermogravimetric (TG) measurements, and IR spectra were performed to analyze the structures and properties of 1 and 2. XRD analyses reveal that compound 1 consists of an open Wells-Dawson anion [Si2W 18O66]16-, a five-nuclear cationic cluster [Ni5(OH)3(H2O)4(CH 3CO2)]6+, free Na+ cations, and protonated 1,3-diaminopropanes. Compound 2 has a similar structure to 1, while a six-nuclear cationic cluster [CoII2CoIII 4(OH)5(H2O)2(CH3CO 2)]10+ replaces the five-nuclear cationic cluster [Ni 5(OH)3(H2O)4(CH3CO 2)]6+ in 1. Magnetic susceptibility measurements indicate antiferromagnetic interactions in 1, and the chirality of compound 2 may bring potential properties of catalysis and optical nonlinearity.

AB - Two new inorganic-organic hybrid compounds Na2(C 3N2H12)4{[Ni5(OH) 3(H2O)4(CH3CO2)][Si 2W18O66]}·12.5H2O (1) and (C3N2H12)3{[CoII 2CoIII4(OH)5(H2O) 2(CH3CO2)][Si2W18O 66]}·6H2O·(C3N2H 10) (2), based on lacunary polyoxometalates and high-nuclear transition-metal clusters, have been synthesized by a new method (solvothermal method). Single crystal XRD, magnetic measurements, nonlinear-optical (NLO) measurements, thermogravimetric (TG) measurements, and IR spectra were performed to analyze the structures and properties of 1 and 2. XRD analyses reveal that compound 1 consists of an open Wells-Dawson anion [Si2W 18O66]16-, a five-nuclear cationic cluster [Ni5(OH)3(H2O)4(CH 3CO2)]6+, free Na+ cations, and protonated 1,3-diaminopropanes. Compound 2 has a similar structure to 1, while a six-nuclear cationic cluster [CoII2CoIII 4(OH)5(H2O)2(CH3CO 2)]10+ replaces the five-nuclear cationic cluster [Ni 5(OH)3(H2O)4(CH3CO 2)]6+ in 1. Magnetic susceptibility measurements indicate antiferromagnetic interactions in 1, and the chirality of compound 2 may bring potential properties of catalysis and optical nonlinearity.

UR - http://www.scopus.com/inward/record.url?scp=84878087319&partnerID=8YFLogxK

U2 - 10.1039/c3dt50155h

DO - 10.1039/c3dt50155h

M3 - 文章

AN - SCOPUS:84878087319

SN - 1477-9226

VL - 42

SP - 8454

EP - 8459

JO - Dalton Transactions

JF - Dalton Transactions

IS - 23

ER -

Syntheses, structures and magnetic properties of two unprecedented hybrid compounds constructed from open Wells-Dawson anions and high-nuclear transition metal clusters

Abstract

Access to Document

Other files and links

Fingerprint

Cite this