Synthesis and crystal structure of [1-(4′-fluorobenzyl)pyridinium] 2[Ni(dto)2] complex(dto2- = dithiooxalate dianion)

Ling Liu; Jing Li Xie; Xiao Ming Ren; Qing Jin Meng

Synthesis and crystal structure of [1-(4′-fluorobenzyl)pyridinium] ₂[Ni(dto)₂] complex(dto^2- = dithiooxalate dianion)

Ling Liu, Jing Li Xie, Xiao Ming Ren, Qing Jin Meng

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The complex [1-(4′-fluorobenzyl)pyridinium]₂[Ni(dto) ₂] (dto^2- means clithiooxalate dianion) has been prepared by reaction of Na₂[Ni(S₂C₂O₂) ₂] and the 1-(4′-fluorobenzyl) pyridinium chloride salt. The crystallographic data for the title complex: triclinic P1, a = 8.5698(8) Å, b =9.3461(9) Å, c = 10.5361(10) Å, α = 67.177 (2)°, β = 67.398(2)°, γ = 79.611(2)°, V = 717.59(12) Å³, Z = 1. The [Ni(dto)₂]^2- anion with the Ni atom lying on an inversion center and exhibits a quasi-planar structure. An extensive hydrogen bond network of C - H⋯ O is clearly observed. The nature and size of cation seems to play an important factor in the type of intermolecular interactions as well as the crystal packing in this kind of complexes.

Original language	English
Pages (from-to)	735-738
Number of pages	4
Journal	Chinese Journal of Inorganic Chemistry
Volume	18
Issue number	7
State	Published - 2002
Externally published	Yes

Keywords

1,2-dithiooxalato ligand
Crystal structure
Nickelate (II) complex
Pyridinium cation

Cite this

@article{46af8d6f902e42bf9a1e5b5c9c1b9d27,

title = "Synthesis and crystal structure of [1-(4′-fluorobenzyl)pyridinium] 2[Ni(dto)2] complex(dto2- = dithiooxalate dianion)",

abstract = "The complex [1-(4′-fluorobenzyl)pyridinium]2[Ni(dto) 2] (dto2- means clithiooxalate dianion) has been prepared by reaction of Na2[Ni(S2C2O2) 2] and the 1-(4′-fluorobenzyl) pyridinium chloride salt. The crystallographic data for the title complex: triclinic P1, a = 8.5698(8) {\AA}, b =9.3461(9) {\AA}, c = 10.5361(10) {\AA}, α = 67.177 (2)°, β = 67.398(2)°, γ = 79.611(2)°, V = 717.59(12) {\AA}3, Z = 1. The [Ni(dto)2]2- anion with the Ni atom lying on an inversion center and exhibits a quasi-planar structure. An extensive hydrogen bond network of C - H⋯ O is clearly observed. The nature and size of cation seems to play an important factor in the type of intermolecular interactions as well as the crystal packing in this kind of complexes.",

keywords = "1,2-dithiooxalato ligand, Crystal structure, Nickelate (II) complex, Pyridinium cation",

author = "Ling Liu and Xie, {Jing Li} and Ren, {Xiao Ming} and Meng, {Qing Jin}",

year = "2002",

language = "英语",

volume = "18",

pages = "735--738",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "7",

}

TY - JOUR

T1 - Synthesis and crystal structure of [1-(4′-fluorobenzyl)pyridinium] 2[Ni(dto)2] complex(dto2- = dithiooxalate dianion)

AU - Liu, Ling

AU - Xie, Jing Li

AU - Ren, Xiao Ming

AU - Meng, Qing Jin

PY - 2002

Y1 - 2002

N2 - The complex [1-(4′-fluorobenzyl)pyridinium]2[Ni(dto) 2] (dto2- means clithiooxalate dianion) has been prepared by reaction of Na2[Ni(S2C2O2) 2] and the 1-(4′-fluorobenzyl) pyridinium chloride salt. The crystallographic data for the title complex: triclinic P1, a = 8.5698(8) Å, b =9.3461(9) Å, c = 10.5361(10) Å, α = 67.177 (2)°, β = 67.398(2)°, γ = 79.611(2)°, V = 717.59(12) Å3, Z = 1. The [Ni(dto)2]2- anion with the Ni atom lying on an inversion center and exhibits a quasi-planar structure. An extensive hydrogen bond network of C - H⋯ O is clearly observed. The nature and size of cation seems to play an important factor in the type of intermolecular interactions as well as the crystal packing in this kind of complexes.

AB - The complex [1-(4′-fluorobenzyl)pyridinium]2[Ni(dto) 2] (dto2- means clithiooxalate dianion) has been prepared by reaction of Na2[Ni(S2C2O2) 2] and the 1-(4′-fluorobenzyl) pyridinium chloride salt. The crystallographic data for the title complex: triclinic P1, a = 8.5698(8) Å, b =9.3461(9) Å, c = 10.5361(10) Å, α = 67.177 (2)°, β = 67.398(2)°, γ = 79.611(2)°, V = 717.59(12) Å3, Z = 1. The [Ni(dto)2]2- anion with the Ni atom lying on an inversion center and exhibits a quasi-planar structure. An extensive hydrogen bond network of C - H⋯ O is clearly observed. The nature and size of cation seems to play an important factor in the type of intermolecular interactions as well as the crystal packing in this kind of complexes.

KW - 1,2-dithiooxalato ligand

KW - Crystal structure

KW - Nickelate (II) complex

KW - Pyridinium cation

UR - http://www.scopus.com/inward/record.url?scp=0347648883&partnerID=8YFLogxK

M3 - 文章

AN - SCOPUS:0347648883

SN - 1001-4861

VL - 18

SP - 735

EP - 738

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 7

ER -

Synthesis and crystal structure of [1-(4′-fluorobenzyl)pyridinium] ₂[Ni(dto)₂] complex(dto^2- = dithiooxalate dianion)

Abstract

Keywords

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