Synthesis and crystal structure of a new cobalt(III) complex with 4-(p-methylphenyl)-3,5-bis(pyridin-2-yl)- 1,2,4-triazole

Dun Ru Zhu; Zuo Xiang Wang; Jun Song; Yi Zhi Li; Da Yan Lan

Synthesis and crystal structure of a new cobalt(III) complex with 4-(p-methylphenyl)-3,5-bis(pyridin-2-yl)- 1,2,4-triazole

Dun Ru Zhu, Zuo Xiang Wang, Jun Song, Yi Zhi Li, Da Yan Lan

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

A new cobalt(II) complex, [CoL₂(NCS)₂] ·2CH₂Cl₂, [L=4-(p-methylphenyl)-3,5-bis(pyridin-2- yl)-1,2,4-triazole], was synthesized and its crystal structure was determined by X-ray analysis. The complex crystallizes in monoclinic system with space group P2₁ / c, a=0.867 40(17), b= 1.4539(3), c=1.781 9(4) nm, β=91.18(3), V= 2.2467(8) nm³ and Z=2. The cobalt atom is in a distorted octahedral environment with two bidentate chelating L ligands in the equatorial plane and two NCS^- ions in the axial positions. CCDC: 251658.

Original language	English
Article number	100-4861(2005)01-0128-05
Pages (from-to)	128-132
Number of pages	5
Journal	Chinese Journal of Inorganic Chemistry
Volume	21
Issue number	1
State	Published - 1 Jan 2005

Keywords

Cobalt(II) complex
Crystal structure
Triazole

Cite this

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title = "Synthesis and crystal structure of a new cobalt(III) complex with 4-(p-methylphenyl)-3,5-bis(pyridin-2-yl)- 1,2,4-triazole",

abstract = "A new cobalt(II) complex, [CoL2(NCS)2] ·2CH2Cl2, [L=4-(p-methylphenyl)-3,5-bis(pyridin-2- yl)-1,2,4-triazole], was synthesized and its crystal structure was determined by X-ray analysis. The complex crystallizes in monoclinic system with space group P21 / c, a=0.867 40(17), b= 1.4539(3), c=1.781 9(4) nm, β=91.18(3), V= 2.2467(8) nm3 and Z=2. The cobalt atom is in a distorted octahedral environment with two bidentate chelating L ligands in the equatorial plane and two NCS- ions in the axial positions. CCDC: 251658.",

keywords = "Cobalt(II) complex, Crystal structure, Triazole",

author = "Zhu, {Dun Ru} and Wang, {Zuo Xiang} and Jun Song and Li, {Yi Zhi} and Lan, {Da Yan}",

year = "2005",

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T1 - Synthesis and crystal structure of a new cobalt(III) complex with 4-(p-methylphenyl)-3,5-bis(pyridin-2-yl)- 1,2,4-triazole

AU - Zhu, Dun Ru

AU - Wang, Zuo Xiang

AU - Song, Jun

AU - Li, Yi Zhi

AU - Lan, Da Yan

PY - 2005/1/1

Y1 - 2005/1/1

N2 - A new cobalt(II) complex, [CoL2(NCS)2] ·2CH2Cl2, [L=4-(p-methylphenyl)-3,5-bis(pyridin-2- yl)-1,2,4-triazole], was synthesized and its crystal structure was determined by X-ray analysis. The complex crystallizes in monoclinic system with space group P21 / c, a=0.867 40(17), b= 1.4539(3), c=1.781 9(4) nm, β=91.18(3), V= 2.2467(8) nm3 and Z=2. The cobalt atom is in a distorted octahedral environment with two bidentate chelating L ligands in the equatorial plane and two NCS- ions in the axial positions. CCDC: 251658.

AB - A new cobalt(II) complex, [CoL2(NCS)2] ·2CH2Cl2, [L=4-(p-methylphenyl)-3,5-bis(pyridin-2- yl)-1,2,4-triazole], was synthesized and its crystal structure was determined by X-ray analysis. The complex crystallizes in monoclinic system with space group P21 / c, a=0.867 40(17), b= 1.4539(3), c=1.781 9(4) nm, β=91.18(3), V= 2.2467(8) nm3 and Z=2. The cobalt atom is in a distorted octahedral environment with two bidentate chelating L ligands in the equatorial plane and two NCS- ions in the axial positions. CCDC: 251658.

KW - Cobalt(II) complex

KW - Crystal structure

KW - Triazole

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M3 - 文章

AN - SCOPUS:12344284896

SN - 1001-4861

VL - 21

SP - 128

EP - 132

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 1

M1 - 100-4861(2005)01-0128-05

ER -

Synthesis and crystal structure of a new cobalt(III) complex with 4-(p-methylphenyl)-3,5-bis(pyridin-2-yl)- 1,2,4-triazole

Abstract

Keywords

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