TY - JOUR
T1 - Synthesis, characterization, and crystal structures of two novel ion-pair complexes based on benzene-1,2-dithiolate ligand
AU - Liu, G. X.
AU - Liu, Y.
AU - Nishihara, S.
AU - Ren, X. M.
PY - 2010/3
Y1 - 2010/3
N2 - Two novel ion-pair complexes, [IBzPy][Ni(Bdt)2] (I) and [IBzDMPy][Ni(Bdt)2] (II) (IBzPy = 1-(4-iodobenzyl)pyridinium, IBzDMPy = 1-(4-iodobenzyl)-3,5-dimethyl-pyridinium, and Bdt = benzene-1,2-dithiolate), have been synthesized and characterized by elemental analysis, IR, cyclic voltammetry, and X-ray single-crystal structure determination. The crystal structure determination reveals that the central Ni atoms in complexes I and II are in slightly distorted square-planar coordination environment. The cyclic voltammetric studies show that there are two oxidation peaks for complexes I and II, which are attributed to Ni(IV/III) and Ni(III/II) redox couples.
AB - Two novel ion-pair complexes, [IBzPy][Ni(Bdt)2] (I) and [IBzDMPy][Ni(Bdt)2] (II) (IBzPy = 1-(4-iodobenzyl)pyridinium, IBzDMPy = 1-(4-iodobenzyl)-3,5-dimethyl-pyridinium, and Bdt = benzene-1,2-dithiolate), have been synthesized and characterized by elemental analysis, IR, cyclic voltammetry, and X-ray single-crystal structure determination. The crystal structure determination reveals that the central Ni atoms in complexes I and II are in slightly distorted square-planar coordination environment. The cyclic voltammetric studies show that there are two oxidation peaks for complexes I and II, which are attributed to Ni(IV/III) and Ni(III/II) redox couples.
UR - http://www.scopus.com/inward/record.url?scp=77950793327&partnerID=8YFLogxK
U2 - 10.1134/S1070328410030103
DO - 10.1134/S1070328410030103
M3 - 文章
AN - SCOPUS:77950793327
SN - 1070-3284
VL - 36
SP - 226
EP - 231
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
IS - 3
ER -