Synthesis, Crystal Structure and Magnetic Properties of a Nickel(II) Coordination Polymer Based the V-Shaped Ligands

Guang Xiang Liu; Xiao Chun Zha; Yan Wang; Sadafumi Nishihara; Xiao Ming Ren

doi:10.1007/s10904-011-9530-6

Synthesis, Crystal Structure and Magnetic Properties of a Nickel(II) Coordination Polymer Based the V-Shaped Ligands

Guang Xiang Liu, Xiao Chun Zha, Yan Wang, Sadafumi Nishihara, Xiao Ming Ren

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A new nickel(II) coordination polymer, Ni ₂(DBA) ₂(BIDPE) ₂(H ₂O) (1) (H ₂DBA = 4,4′-methylenedibenzoic acid and BIDPE = 4,4′-bis(imidazole-l-yl)diphenyl ether), has been prepared by hydrothermal synthesis and structurally characterized by IR, elemental analysis, TGA and single crystal X-ray diffraction. Complex 1 features a one-dimensional chain structure based on triply bridged binuclear units, which is further interlinked into a higher-dimensional supramolecular framework by intermolecular weak interactions. Variable-temperature magnetic data shows weak antiferromagnetic behavior in 1. Graphical Abstract: A new nickel(II) coordination polymer, Ni ₂(DBA)(BIDPE)(H ₂O), has been prepared by hydrothermal synthesis and features a one-dimensional chain structure based on triply bridged binuclear units. Variable-temperature magnetic data shows weak antiferromagnetic behavior[Figure not available: see fulltext.]

Original language	English
Pages (from-to)	258-263
Number of pages	6
Journal	Journal of Inorganic and Organometallic Polymers and Materials
Volume	22
Issue number	1
DOIs	https://doi.org/10.1007/s10904-011-9530-6
State	Published - Jan 2012
Externally published	Yes

Keywords

Carboxylate
Crystal structure
Magnetic property
Nickel(II) complex

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10.1007/s10904-011-9530-6

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@article{1052171a4c714828bb31d24c7a6abaa9,

title = "Synthesis, Crystal Structure and Magnetic Properties of a Nickel(II) Coordination Polymer Based the V-Shaped Ligands",

abstract = "A new nickel(II) coordination polymer, Ni 2(DBA) 2(BIDPE) 2(H 2O) (1) (H 2DBA = 4,4′-methylenedibenzoic acid and BIDPE = 4,4′-bis(imidazole-l-yl)diphenyl ether), has been prepared by hydrothermal synthesis and structurally characterized by IR, elemental analysis, TGA and single crystal X-ray diffraction. Complex 1 features a one-dimensional chain structure based on triply bridged binuclear units, which is further interlinked into a higher-dimensional supramolecular framework by intermolecular weak interactions. Variable-temperature magnetic data shows weak antiferromagnetic behavior in 1. Graphical Abstract: A new nickel(II) coordination polymer, Ni 2(DBA)(BIDPE)(H 2O), has been prepared by hydrothermal synthesis and features a one-dimensional chain structure based on triply bridged binuclear units. Variable-temperature magnetic data shows weak antiferromagnetic behavior[Figure not available: see fulltext.]",

keywords = "Carboxylate, Crystal structure, Magnetic property, Nickel(II) complex",

author = "Liu, {Guang Xiang} and Zha, {Xiao Chun} and Yan Wang and Sadafumi Nishihara and Ren, {Xiao Ming}",

year = "2012",

month = jan,

doi = "10.1007/s10904-011-9530-6",

language = "英语",

volume = "22",

pages = "258--263",

journal = "Journal of Inorganic and Organometallic Polymers and Materials",

issn = "1574-1443",

publisher = "Springer New York",

number = "1",

}

TY - JOUR

T1 - Synthesis, Crystal Structure and Magnetic Properties of a Nickel(II) Coordination Polymer Based the V-Shaped Ligands

AU - Liu, Guang Xiang

AU - Zha, Xiao Chun

AU - Wang, Yan

AU - Nishihara, Sadafumi

AU - Ren, Xiao Ming

PY - 2012/1

Y1 - 2012/1

N2 - A new nickel(II) coordination polymer, Ni 2(DBA) 2(BIDPE) 2(H 2O) (1) (H 2DBA = 4,4′-methylenedibenzoic acid and BIDPE = 4,4′-bis(imidazole-l-yl)diphenyl ether), has been prepared by hydrothermal synthesis and structurally characterized by IR, elemental analysis, TGA and single crystal X-ray diffraction. Complex 1 features a one-dimensional chain structure based on triply bridged binuclear units, which is further interlinked into a higher-dimensional supramolecular framework by intermolecular weak interactions. Variable-temperature magnetic data shows weak antiferromagnetic behavior in 1. Graphical Abstract: A new nickel(II) coordination polymer, Ni 2(DBA)(BIDPE)(H 2O), has been prepared by hydrothermal synthesis and features a one-dimensional chain structure based on triply bridged binuclear units. Variable-temperature magnetic data shows weak antiferromagnetic behavior[Figure not available: see fulltext.]

AB - A new nickel(II) coordination polymer, Ni 2(DBA) 2(BIDPE) 2(H 2O) (1) (H 2DBA = 4,4′-methylenedibenzoic acid and BIDPE = 4,4′-bis(imidazole-l-yl)diphenyl ether), has been prepared by hydrothermal synthesis and structurally characterized by IR, elemental analysis, TGA and single crystal X-ray diffraction. Complex 1 features a one-dimensional chain structure based on triply bridged binuclear units, which is further interlinked into a higher-dimensional supramolecular framework by intermolecular weak interactions. Variable-temperature magnetic data shows weak antiferromagnetic behavior in 1. Graphical Abstract: A new nickel(II) coordination polymer, Ni 2(DBA)(BIDPE)(H 2O), has been prepared by hydrothermal synthesis and features a one-dimensional chain structure based on triply bridged binuclear units. Variable-temperature magnetic data shows weak antiferromagnetic behavior[Figure not available: see fulltext.]

KW - Carboxylate

KW - Crystal structure

KW - Magnetic property

KW - Nickel(II) complex

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U2 - 10.1007/s10904-011-9530-6

DO - 10.1007/s10904-011-9530-6

M3 - 文章

AN - SCOPUS:84856226468

SN - 1574-1443

VL - 22

SP - 258

EP - 263

JO - Journal of Inorganic and Organometallic Polymers and Materials

JF - Journal of Inorganic and Organometallic Polymers and Materials

IS - 1

ER -

Synthesis, Crystal Structure and Magnetic Properties of a Nickel(II) Coordination Polymer Based the V-Shaped Ligands

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