Synthesis, crystal structure, and magnetic property of a new nickel(III) complex constructed from 1,2-benezedithiolate

Guang Xiang Liu; Ying Liu; Sadafumi Nishihara; Xiao Ming Ren

doi:10.1080/15533174.2010.492554

Synthesis, crystal structure, and magnetic property of a new nickel(III) complex constructed from 1,2-benezedithiolate

Guang Xiang Liu, Ying Liu, Sadafumi Nishihara, Xiao Ming Ren

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The new complex, [IBzPyCH₃][Ni(bdt)₂] (1), has been synthesized and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction, in which [IBzPyCH₃]⁺ = 1-(4-iodobenzyl)-3-methylpyridinium and bdt^2- = 1,2-benzene- dithiolate. The X-ray structure analysis shows that the anions are centrosymmetric, the two nonequivalent anions form different uniform-spaced stacking pattern and the weak H-bonding interactions of C-H⋯S were observed in 1. The temperature dependence of magnetic susceptibilities of 1 indicates ferromagnetic behavior in the antiferromagnetic exchange system, which may arise from spin-canting.

Original language	English
Pages (from-to)	416-420
Number of pages	5
Journal	Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry
Volume	40
Issue number	6
DOIs	https://doi.org/10.1080/15533174.2010.492554
State	Published - Jul 2010
Externally published	Yes

Keywords

crystal structure
magnetism
nickel(III) thiolate complex
spin-canting

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10.1080/15533174.2010.492554

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title = "Synthesis, crystal structure, and magnetic property of a new nickel(III) complex constructed from 1,2-benezedithiolate",

abstract = "The new complex, [IBzPyCH3][Ni(bdt)2] (1), has been synthesized and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction, in which [IBzPyCH3]+ = 1-(4-iodobenzyl)-3-methylpyridinium and bdt2- = 1,2-benzene- dithiolate. The X-ray structure analysis shows that the anions are centrosymmetric, the two nonequivalent anions form different uniform-spaced stacking pattern and the weak H-bonding interactions of C-H⋯S were observed in 1. The temperature dependence of magnetic susceptibilities of 1 indicates ferromagnetic behavior in the antiferromagnetic exchange system, which may arise from spin-canting.",

keywords = "crystal structure, magnetism, nickel(III) thiolate complex, spin-canting",

author = "Liu, {Guang Xiang} and Ying Liu and Sadafumi Nishihara and Ren, {Xiao Ming}",

year = "2010",

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doi = "10.1080/15533174.2010.492554",

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TY - JOUR

T1 - Synthesis, crystal structure, and magnetic property of a new nickel(III) complex constructed from 1,2-benezedithiolate

AU - Liu, Guang Xiang

AU - Liu, Ying

AU - Nishihara, Sadafumi

AU - Ren, Xiao Ming

PY - 2010/7

Y1 - 2010/7

N2 - The new complex, [IBzPyCH3][Ni(bdt)2] (1), has been synthesized and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction, in which [IBzPyCH3]+ = 1-(4-iodobenzyl)-3-methylpyridinium and bdt2- = 1,2-benzene- dithiolate. The X-ray structure analysis shows that the anions are centrosymmetric, the two nonequivalent anions form different uniform-spaced stacking pattern and the weak H-bonding interactions of C-H⋯S were observed in 1. The temperature dependence of magnetic susceptibilities of 1 indicates ferromagnetic behavior in the antiferromagnetic exchange system, which may arise from spin-canting.

AB - The new complex, [IBzPyCH3][Ni(bdt)2] (1), has been synthesized and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction, in which [IBzPyCH3]+ = 1-(4-iodobenzyl)-3-methylpyridinium and bdt2- = 1,2-benzene- dithiolate. The X-ray structure analysis shows that the anions are centrosymmetric, the two nonequivalent anions form different uniform-spaced stacking pattern and the weak H-bonding interactions of C-H⋯S were observed in 1. The temperature dependence of magnetic susceptibilities of 1 indicates ferromagnetic behavior in the antiferromagnetic exchange system, which may arise from spin-canting.

KW - crystal structure

KW - magnetism

KW - nickel(III) thiolate complex

KW - spin-canting

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U2 - 10.1080/15533174.2010.492554

DO - 10.1080/15533174.2010.492554

M3 - 文章

AN - SCOPUS:77954756333

SN - 1553-3174

VL - 40

SP - 416

EP - 420

JO - Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

JF - Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

IS - 6

ER -

Synthesis, crystal structure, and magnetic property of a new nickel(III) complex constructed from 1,2-benezedithiolate

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Keywords

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