Synthesis, crystal structure, and magnetic property of a new nickel(III) complex constructed from 1,2-benezedithiolate

Guang Xiang Liu, Ying Liu, Sadafumi Nishihara, Xiao Ming Ren

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

The new complex, [IBzPyCH3][Ni(bdt)2] (1), has been synthesized and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction, in which [IBzPyCH3]+ = 1-(4-iodobenzyl)-3-methylpyridinium and bdt2- = 1,2-benzene- dithiolate. The X-ray structure analysis shows that the anions are centrosymmetric, the two nonequivalent anions form different uniform-spaced stacking pattern and the weak H-bonding interactions of C-H⋯S were observed in 1. The temperature dependence of magnetic susceptibilities of 1 indicates ferromagnetic behavior in the antiferromagnetic exchange system, which may arise from spin-canting.

Original languageEnglish
Pages (from-to)416-420
Number of pages5
JournalSynthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry
Volume40
Issue number6
DOIs
StatePublished - Jul 2010
Externally publishedYes

Keywords

  • crystal structure
  • magnetism
  • nickel(III) thiolate complex
  • spin-canting

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