Synthesis of vinylic sulfones in aqueous media

Jeffrey Goh; Manikantha Maraswami; Teck Peng Loh

doi:10.1021/acs.orglett.0c04257

Synthesis of vinylic sulfones in aqueous media

Jeffrey Goh, Manikantha Maraswami, Teck Peng Loh

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

A green method for the sulfination of allenic carbonyl compounds to access a wide variety of vinylic sulfones is developed. This reaction works in aqueous media under very mild conditions. This reaction is atom economic. A wide variety of vinylic sulfones could be obtained in moderate to excellent yields with wide functional group tolerance. The efficiency of this method is demonstrated in some reactions where the desired products can be isolated by filtration.

Original language	English
Pages (from-to)	1060-1065
Number of pages	6
Journal	Organic Letters
Volume	23
Issue number	3
DOIs	https://doi.org/10.1021/acs.orglett.0c04257
State	Published - 5 Feb 2021
Externally published	Yes

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title = "Synthesis of vinylic sulfones in aqueous media",

abstract = "A green method for the sulfination of allenic carbonyl compounds to access a wide variety of vinylic sulfones is developed. This reaction works in aqueous media under very mild conditions. This reaction is atom economic. A wide variety of vinylic sulfones could be obtained in moderate to excellent yields with wide functional group tolerance. The efficiency of this method is demonstrated in some reactions where the desired products can be isolated by filtration.",

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N2 - A green method for the sulfination of allenic carbonyl compounds to access a wide variety of vinylic sulfones is developed. This reaction works in aqueous media under very mild conditions. This reaction is atom economic. A wide variety of vinylic sulfones could be obtained in moderate to excellent yields with wide functional group tolerance. The efficiency of this method is demonstrated in some reactions where the desired products can be isolated by filtration.

AB - A green method for the sulfination of allenic carbonyl compounds to access a wide variety of vinylic sulfones is developed. This reaction works in aqueous media under very mild conditions. This reaction is atom economic. A wide variety of vinylic sulfones could be obtained in moderate to excellent yields with wide functional group tolerance. The efficiency of this method is demonstrated in some reactions where the desired products can be isolated by filtration.

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Synthesis of vinylic sulfones in aqueous media

Abstract

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