The inclusion complex of ferrocene with a dithiolene functionalized β-cyclodextrin

Changsheng Lu; Xiaoming Ren; Ling Liu; Yue Zhang; Chuanjiang Hu; Huizhen Zhu; Qingjin Meng

doi:10.1023/A:1020455612326

The inclusion complex of ferrocene with a dithiolene functionalized β-cyclodextrin

Changsheng Lu, Xiaoming Ren, Ling Liu, Yue Zhang, Chuanjiang Hu, Huizhen Zhu, Qingjin Meng

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A new β-cyclodextrin derivative with the anion side-arm, mono[6-deoxy-6-(2-sodium thio-1,2-dicyane ethylenylthio)]-β-cyclodextrin (6-mnt-β-CD), and its inclusion complex with ferrocene (6-mnt-β -CD/Fc), have been prepared and characterized by elemental analysis, IR spectroscopy, UV spectroscopy, mass spectrometry, ¹³C-NMR spectroscopy, thermogravimetry, and cyclic voltammetry (CV). Thermogravimetry analysis of the compound shows that the thermal stabilities of both the host and the guest in the inclusion complex have been greatly improved due to an additional interaction between the side-arm of the host and the guest. The interplay between the guest and the host with side-arm in the complex resulted in smaller positive potential shifts in CV compared to that in the inclusion complex β-CD/Fc.

Original language	English
Pages (from-to)	19-23
Number of pages	5
Journal	Journal of Inclusion Phenomena
Volume	43
Issue number	1-2
DOIs	https://doi.org/10.1023/A:1020455612326
State	Published - 2002
Externally published	Yes

Keywords

Cyclic voltammetry
Differential thermogravimetry
Ferrocene
Inclusion complex
Mono[6-deoxy-6-(2-sodium thio-1,2-dicyane ethylenylthio)]-β -cyclodextrin

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title = "The inclusion complex of ferrocene with a dithiolene functionalized β-cyclodextrin",

abstract = "A new β-cyclodextrin derivative with the anion side-arm, mono[6-deoxy-6-(2-sodium thio-1,2-dicyane ethylenylthio)]-β-cyclodextrin (6-mnt-β-CD), and its inclusion complex with ferrocene (6-mnt-β -CD/Fc), have been prepared and characterized by elemental analysis, IR spectroscopy, UV spectroscopy, mass spectrometry, 13C-NMR spectroscopy, thermogravimetry, and cyclic voltammetry (CV). Thermogravimetry analysis of the compound shows that the thermal stabilities of both the host and the guest in the inclusion complex have been greatly improved due to an additional interaction between the side-arm of the host and the guest. The interplay between the guest and the host with side-arm in the complex resulted in smaller positive potential shifts in CV compared to that in the inclusion complex β-CD/Fc.",

keywords = "Cyclic voltammetry, Differential thermogravimetry, Ferrocene, Inclusion complex, Mono[6-deoxy-6-(2-sodium thio-1,2-dicyane ethylenylthio)]-β -cyclodextrin",

author = "Changsheng Lu and Xiaoming Ren and Ling Liu and Yue Zhang and Chuanjiang Hu and Huizhen Zhu and Qingjin Meng",

year = "2002",

doi = "10.1023/A:1020455612326",

language = "英语",

volume = "43",

pages = "19--23",

journal = "Journal of Inclusion Phenomena",

issn = "0923-0750",

publisher = "Springer",

number = "1-2",

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TY - JOUR

T1 - The inclusion complex of ferrocene with a dithiolene functionalized β-cyclodextrin

AU - Lu, Changsheng

AU - Ren, Xiaoming

AU - Liu, Ling

AU - Zhang, Yue

AU - Hu, Chuanjiang

AU - Zhu, Huizhen

AU - Meng, Qingjin

PY - 2002

Y1 - 2002

N2 - A new β-cyclodextrin derivative with the anion side-arm, mono[6-deoxy-6-(2-sodium thio-1,2-dicyane ethylenylthio)]-β-cyclodextrin (6-mnt-β-CD), and its inclusion complex with ferrocene (6-mnt-β -CD/Fc), have been prepared and characterized by elemental analysis, IR spectroscopy, UV spectroscopy, mass spectrometry, 13C-NMR spectroscopy, thermogravimetry, and cyclic voltammetry (CV). Thermogravimetry analysis of the compound shows that the thermal stabilities of both the host and the guest in the inclusion complex have been greatly improved due to an additional interaction between the side-arm of the host and the guest. The interplay between the guest and the host with side-arm in the complex resulted in smaller positive potential shifts in CV compared to that in the inclusion complex β-CD/Fc.

AB - A new β-cyclodextrin derivative with the anion side-arm, mono[6-deoxy-6-(2-sodium thio-1,2-dicyane ethylenylthio)]-β-cyclodextrin (6-mnt-β-CD), and its inclusion complex with ferrocene (6-mnt-β -CD/Fc), have been prepared and characterized by elemental analysis, IR spectroscopy, UV spectroscopy, mass spectrometry, 13C-NMR spectroscopy, thermogravimetry, and cyclic voltammetry (CV). Thermogravimetry analysis of the compound shows that the thermal stabilities of both the host and the guest in the inclusion complex have been greatly improved due to an additional interaction between the side-arm of the host and the guest. The interplay between the guest and the host with side-arm in the complex resulted in smaller positive potential shifts in CV compared to that in the inclusion complex β-CD/Fc.

KW - Cyclic voltammetry

KW - Differential thermogravimetry

KW - Ferrocene

KW - Inclusion complex

KW - Mono[6-deoxy-6-(2-sodium thio-1,2-dicyane ethylenylthio)]-β -cyclodextrin

UR - http://www.scopus.com/inward/record.url?scp=0347655714&partnerID=8YFLogxK

U2 - 10.1023/A:1020455612326

DO - 10.1023/A:1020455612326

M3 - 文章

AN - SCOPUS:0347655714

SN - 0923-0750

VL - 43

SP - 19

EP - 23

JO - Journal of Inclusion Phenomena

JF - Journal of Inclusion Phenomena

IS - 1-2

ER -

The inclusion complex of ferrocene with a dithiolene functionalized β-cyclodextrin

Abstract

Keywords

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