Thermodynamic analysis for determination of solid-liquid equilibrium of dibenzothiophene in a binary solvent of formic acid and butan-1-ol between (278.15 and 333.15) K

Qi Zhang; Yonghong Hu; Yang Yang; Cuicui Cao; Limin Cheng; Ying Shi; Wenge Yang

doi:10.1016/j.fluid.2015.08.023

Thermodynamic analysis for determination of solid-liquid equilibrium of dibenzothiophene in a binary solvent of formic acid and butan-1-ol between (278.15 and 333.15) K

Qi Zhang, Yonghong Hu, Yang Yang, Cuicui Cao, Limin Cheng, Ying Shi, Wenge Yang

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

In this paper, we focused on solubility and solution thermodynamics of dibenzothiophene. By gravimetric method, the solubility of dibenzothiophene was measured in (formic acid + butan-1-ol) binary solvent mixtures from 278.15 K to 333.15 K under atmosphere pressure. The solubility data were fitted using modified Apelblat equation, a variant of the combined nearly ideal binary solvent/Redich-Kister (CNIBS/R-K) model and Jouyban-Acree model. Computational results showed that the modified Apelblat equation was superior to the other two equations. In addition, the thermodynamic properties of the solution process, including the Gibbs energy, enthalpy, and entropy were calculated by the van't Hoff analysis. The experimental results showed that formic acid could be used as effective anti-solvents in the crystallization process.

Original language	English
Pages (from-to)	94-99
Number of pages	6
Journal	Fluid Phase Equilibria
Volume	408
DOIs	https://doi.org/10.1016/j.fluid.2015.08.023
State	Published - 25 Jan 2016

Keywords

Apelblat equation
CNIBS/R-K
Dibenzothiophene
Jouyban-Acree model
Van't Hoff analysis

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10.1016/j.fluid.2015.08.023

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title = "Thermodynamic analysis for determination of solid-liquid equilibrium of dibenzothiophene in a binary solvent of formic acid and butan-1-ol between (278.15 and 333.15) K",

abstract = "In this paper, we focused on solubility and solution thermodynamics of dibenzothiophene. By gravimetric method, the solubility of dibenzothiophene was measured in (formic acid + butan-1-ol) binary solvent mixtures from 278.15 K to 333.15 K under atmosphere pressure. The solubility data were fitted using modified Apelblat equation, a variant of the combined nearly ideal binary solvent/Redich-Kister (CNIBS/R-K) model and Jouyban-Acree model. Computational results showed that the modified Apelblat equation was superior to the other two equations. In addition, the thermodynamic properties of the solution process, including the Gibbs energy, enthalpy, and entropy were calculated by the van't Hoff analysis. The experimental results showed that formic acid could be used as effective anti-solvents in the crystallization process.",

keywords = "Apelblat equation, CNIBS/R-K, Dibenzothiophene, Jouyban-Acree model, Van't Hoff analysis",

author = "Qi Zhang and Yonghong Hu and Yang Yang and Cuicui Cao and Limin Cheng and Ying Shi and Wenge Yang",

note = "Publisher Copyright: {\textcopyright} 2015 Elsevier B.V.",

year = "2016",

month = jan,

day = "25",

doi = "10.1016/j.fluid.2015.08.023",

language = "英语",

volume = "408",

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T1 - Thermodynamic analysis for determination of solid-liquid equilibrium of dibenzothiophene in a binary solvent of formic acid and butan-1-ol between (278.15 and 333.15) K

AU - Zhang, Qi

AU - Hu, Yonghong

AU - Yang, Yang

AU - Cao, Cuicui

AU - Cheng, Limin

AU - Shi, Ying

AU - Yang, Wenge

PY - 2016/1/25

Y1 - 2016/1/25

N2 - In this paper, we focused on solubility and solution thermodynamics of dibenzothiophene. By gravimetric method, the solubility of dibenzothiophene was measured in (formic acid + butan-1-ol) binary solvent mixtures from 278.15 K to 333.15 K under atmosphere pressure. The solubility data were fitted using modified Apelblat equation, a variant of the combined nearly ideal binary solvent/Redich-Kister (CNIBS/R-K) model and Jouyban-Acree model. Computational results showed that the modified Apelblat equation was superior to the other two equations. In addition, the thermodynamic properties of the solution process, including the Gibbs energy, enthalpy, and entropy were calculated by the van't Hoff analysis. The experimental results showed that formic acid could be used as effective anti-solvents in the crystallization process.

AB - In this paper, we focused on solubility and solution thermodynamics of dibenzothiophene. By gravimetric method, the solubility of dibenzothiophene was measured in (formic acid + butan-1-ol) binary solvent mixtures from 278.15 K to 333.15 K under atmosphere pressure. The solubility data were fitted using modified Apelblat equation, a variant of the combined nearly ideal binary solvent/Redich-Kister (CNIBS/R-K) model and Jouyban-Acree model. Computational results showed that the modified Apelblat equation was superior to the other two equations. In addition, the thermodynamic properties of the solution process, including the Gibbs energy, enthalpy, and entropy were calculated by the van't Hoff analysis. The experimental results showed that formic acid could be used as effective anti-solvents in the crystallization process.

KW - Apelblat equation

KW - CNIBS/R-K

KW - Dibenzothiophene

KW - Jouyban-Acree model

KW - Van't Hoff analysis

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U2 - 10.1016/j.fluid.2015.08.023

DO - 10.1016/j.fluid.2015.08.023

M3 - 文章

AN - SCOPUS:84940779601

SN - 0378-3812

VL - 408

SP - 94

EP - 99

JO - Fluid Phase Equilibria

JF - Fluid Phase Equilibria

ER -

Thermodynamic analysis for determination of solid-liquid equilibrium of dibenzothiophene in a binary solvent of formic acid and butan-1-ol between (278.15 and 333.15) K

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