Three Zn(II)/Cd(II)/Mn(II) coordination polymers based on a 2-hydroxy-N-(1H-tetrazol-5-yl) benzamide ligand: Structures, and magnetic and photoluminescence properties

Yang Zou, Jing Chen, Yuan Yuan Li, Li Li, Jian Lan Liu, Xiao Ming Ren

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3 Scopus citations

Abstract

Three coordination polymers, {[Zn(L)2]·H2O}n (1), {[Cd(L)2]·H2O}n (2) and {[Mn(L)2]·H2O}n (3) (HL = 2-hydroxy-N-1H-tetrazol-5-ylbenzamide), have been prepared under hydrothermal conditions. X-ray diffraction analysis reveals that compounds 1-3 are isomorphous, showing an interdigitated 3-D framework with 1-D channels. Fluorescence studies show that the emissions of complexes 1-2 are attributed to the ligand π-π∗ transition. Magnetic studies indicate that compound 3 exhibits antiferromagnetic properties.

Original languageEnglish
Pages (from-to)78642-78647
Number of pages6
JournalRSC Advances
Volume5
Issue number96
DOIs
StatePublished - 11 Sep 2015

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