Two-dimensional molecular magnets based on [Pt(mnt)2] - ions: Structures and magnetic properties

X. M. Ren; S. Nishihara; T. Akutagawa; T. Nakamura; J. L. Xie; Q. J. Meng

doi:10.1016/j.poly.2005.03.034

Two-dimensional molecular magnets based on [Pt(mnt)₂] ^- ions: Structures and magnetic properties

X. M. Ren, S. Nishihara, T. Akutagawa, T. Nakamura, J. L. Xie, Q. J. Meng

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Two compounds of composition [FBzPy][Pt(mnt)₂] (1) and [FBzPy][Pt(mnt)₂]·0.25-MeCN (2) ([FBzPy]⁺ = 1-(4′-fluorobenzyl)pyridinium and mnt^2- = maleonitriledithiolate) were prepared and their crystal structures were determined. The solvent molecule, MeCN, incorporated into lattice leads the anionic stacking pattern to be distinct between 1 and 2. The regular anionic stacking columns are connected by the anionic dimers to construct into 2D anionic networks in 1, while the anionic fourfold subunit develop into anionic layers though lateral S⋯S interactions in 2. As for two compounds, the magnetic susceptibilities in 2-350 K were measured, and the magnetic exchange schemes were built based on the analyses both crystal structures and extended Hückel molecular orbital calculations. The magnetic coupling model of an alternating AFM Heisenberg chain with an isolated AFM coupling dimer was dealt with 1, while a spin dimer with s = 1/2 with 2, and the magnetic coupling parameters were further gained via simulating the temperature dependent magnetic susceptibility data of two compounds.

Original language	English
Pages (from-to)	2160-2164
Number of pages	5
Journal	Polyhedron
Volume	24
Issue number	16-17
DOIs	https://doi.org/10.1016/j.poly.2005.03.034
State	Published - 17 Nov 2005
Externally published	Yes

Keywords

Crystal structure
Extended Hückel molecular orbital calculation
Magnetic property
Two-dimensional molecular magnet

Access to Document

10.1016/j.poly.2005.03.034

Cite this

@article{1d419298487e4a0cbc77908cad821547,

title = "Two-dimensional molecular magnets based on [Pt(mnt)2] - ions: Structures and magnetic properties",

abstract = "Two compounds of composition [FBzPy][Pt(mnt)2] (1) and [FBzPy][Pt(mnt)2]·0.25-MeCN (2) ([FBzPy]+ = 1-(4′-fluorobenzyl)pyridinium and mnt2- = maleonitriledithiolate) were prepared and their crystal structures were determined. The solvent molecule, MeCN, incorporated into lattice leads the anionic stacking pattern to be distinct between 1 and 2. The regular anionic stacking columns are connected by the anionic dimers to construct into 2D anionic networks in 1, while the anionic fourfold subunit develop into anionic layers though lateral S⋯S interactions in 2. As for two compounds, the magnetic susceptibilities in 2-350 K were measured, and the magnetic exchange schemes were built based on the analyses both crystal structures and extended H{\"u}ckel molecular orbital calculations. The magnetic coupling model of an alternating AFM Heisenberg chain with an isolated AFM coupling dimer was dealt with 1, while a spin dimer with s = 1/2 with 2, and the magnetic coupling parameters were further gained via simulating the temperature dependent magnetic susceptibility data of two compounds.",

keywords = "Crystal structure, Extended H{\"u}ckel molecular orbital calculation, Magnetic property, Two-dimensional molecular magnet",

author = "Ren, {X. M.} and S. Nishihara and T. Akutagawa and T. Nakamura and Xie, {J. L.} and Meng, {Q. J.}",

year = "2005",

month = nov,

day = "17",

doi = "10.1016/j.poly.2005.03.034",

language = "英语",

volume = "24",

pages = "2160--2164",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd",

number = "16-17",

}

TY - JOUR

T1 - Two-dimensional molecular magnets based on [Pt(mnt)2] - ions

T2 - Structures and magnetic properties

AU - Ren, X. M.

AU - Nishihara, S.

AU - Akutagawa, T.

AU - Nakamura, T.

AU - Xie, J. L.

AU - Meng, Q. J.

PY - 2005/11/17

Y1 - 2005/11/17

N2 - Two compounds of composition [FBzPy][Pt(mnt)2] (1) and [FBzPy][Pt(mnt)2]·0.25-MeCN (2) ([FBzPy]+ = 1-(4′-fluorobenzyl)pyridinium and mnt2- = maleonitriledithiolate) were prepared and their crystal structures were determined. The solvent molecule, MeCN, incorporated into lattice leads the anionic stacking pattern to be distinct between 1 and 2. The regular anionic stacking columns are connected by the anionic dimers to construct into 2D anionic networks in 1, while the anionic fourfold subunit develop into anionic layers though lateral S⋯S interactions in 2. As for two compounds, the magnetic susceptibilities in 2-350 K were measured, and the magnetic exchange schemes were built based on the analyses both crystal structures and extended Hückel molecular orbital calculations. The magnetic coupling model of an alternating AFM Heisenberg chain with an isolated AFM coupling dimer was dealt with 1, while a spin dimer with s = 1/2 with 2, and the magnetic coupling parameters were further gained via simulating the temperature dependent magnetic susceptibility data of two compounds.

AB - Two compounds of composition [FBzPy][Pt(mnt)2] (1) and [FBzPy][Pt(mnt)2]·0.25-MeCN (2) ([FBzPy]+ = 1-(4′-fluorobenzyl)pyridinium and mnt2- = maleonitriledithiolate) were prepared and their crystal structures were determined. The solvent molecule, MeCN, incorporated into lattice leads the anionic stacking pattern to be distinct between 1 and 2. The regular anionic stacking columns are connected by the anionic dimers to construct into 2D anionic networks in 1, while the anionic fourfold subunit develop into anionic layers though lateral S⋯S interactions in 2. As for two compounds, the magnetic susceptibilities in 2-350 K were measured, and the magnetic exchange schemes were built based on the analyses both crystal structures and extended Hückel molecular orbital calculations. The magnetic coupling model of an alternating AFM Heisenberg chain with an isolated AFM coupling dimer was dealt with 1, while a spin dimer with s = 1/2 with 2, and the magnetic coupling parameters were further gained via simulating the temperature dependent magnetic susceptibility data of two compounds.

KW - Crystal structure

KW - Extended Hückel molecular orbital calculation

KW - Magnetic property

KW - Two-dimensional molecular magnet

UR - http://www.scopus.com/inward/record.url?scp=27644591355&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2005.03.034

DO - 10.1016/j.poly.2005.03.034

M3 - 文章

AN - SCOPUS:27644591355

SN - 0277-5387

VL - 24

SP - 2160

EP - 2164

JO - Polyhedron

JF - Polyhedron

IS - 16-17

ER -

Two-dimensional molecular magnets based on [Pt(mnt)₂] ^- ions: Structures and magnetic properties

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this