Two Series of Main-Group Heterometallic Selenides Synthesized in Two Different Types of Ionic Liquids

Ji Ming Yu, Ji Peng Yu, Ning Wang, Lu Lu Xiao, Huan Wang, Qi Xu, Bing Zheng, Fang Fang Cheng, Wei Wei Xiong

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

Imidazolium-based ionic liquids have been widely applied in the synthesis of organic hybrid chalcogenidometalates, while the other types of ionic liquids are rarely tried. Reported here is the first application of a pyridinium-based ionic liquid in the preparation of two main-group heterometallic selenides featuring isomorphic three-dimensional frameworks. Of particular interest is that three gallium-tin selenides possessing another type of three-dimensional framework have been prepared by replacing the pyridinium-based ionic liquid with imidalolium-based ionic liquids under the same reaction conditions.

Original languageEnglish
Pages (from-to)4337-4341
Number of pages5
JournalInorganic Chemistry
Volume60
Issue number7
DOIs
StatePublished - 5 Apr 2021

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