Variable photophysical properties of phosphorescent iridium(III) complexes triggered by closo- and nido-carborane substitution

Chao Shi; Huibin Sun; Xiao Tang; Wen Lv; Hong Yan; Qiang Zhao; Jingxia Wang; Wei Huang

doi:10.1002/anie.201307333

Variable photophysical properties of phosphorescent iridium(III) complexes triggered by closo- and nido-carborane substitution

Chao Shi, Huibin Sun, Xiao Tang, Wen Lv, Hong Yan, Qiang Zhao, Jingxia Wang, Wei Huang

Research output: Contribution to journal › Article › peer-review

195 Scopus citations

Abstract

Phosphorescent iridium(III) complexes with three bidentate carborane-functionalized ligands have been synthesized. The luminescent efficiency of the o-carborane-based facial complex fac-o shows solvent-molecule dependence both in solution and solid state that is related to the dielectric constant. The water-soluble and high phosphorescence-efficient nido complex nido-fac-o can be used in fluorescence lifetime bioimaging.

Original language	English
Pages (from-to)	13434-13438
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	50
DOIs	https://doi.org/10.1002/anie.201307333
State	Published - 9 Dec 2013
Externally published	Yes

Keywords

bioimaging
carboranes
iridium
phosphorescence

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10.1002/anie.201307333

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abstract = "Phosphorescent iridium(III) complexes with three bidentate carborane-functionalized ligands have been synthesized. The luminescent efficiency of the o-carborane-based facial complex fac-o shows solvent-molecule dependence both in solution and solid state that is related to the dielectric constant. The water-soluble and high phosphorescence-efficient nido complex nido-fac-o can be used in fluorescence lifetime bioimaging.",

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author = "Chao Shi and Huibin Sun and Xiao Tang and Wen Lv and Hong Yan and Qiang Zhao and Jingxia Wang and Wei Huang",

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T1 - Variable photophysical properties of phosphorescent iridium(III) complexes triggered by closo- and nido-carborane substitution

AU - Shi, Chao

AU - Sun, Huibin

AU - Tang, Xiao

AU - Lv, Wen

AU - Yan, Hong

AU - Zhao, Qiang

AU - Wang, Jingxia

AU - Huang, Wei

PY - 2013/12/9

Y1 - 2013/12/9

N2 - Phosphorescent iridium(III) complexes with three bidentate carborane-functionalized ligands have been synthesized. The luminescent efficiency of the o-carborane-based facial complex fac-o shows solvent-molecule dependence both in solution and solid state that is related to the dielectric constant. The water-soluble and high phosphorescence-efficient nido complex nido-fac-o can be used in fluorescence lifetime bioimaging.

AB - Phosphorescent iridium(III) complexes with three bidentate carborane-functionalized ligands have been synthesized. The luminescent efficiency of the o-carborane-based facial complex fac-o shows solvent-molecule dependence both in solution and solid state that is related to the dielectric constant. The water-soluble and high phosphorescence-efficient nido complex nido-fac-o can be used in fluorescence lifetime bioimaging.

KW - bioimaging

KW - carboranes

KW - iridium

KW - phosphorescence

UR - http://www.scopus.com/inward/record.url?scp=84889684547&partnerID=8YFLogxK

U2 - 10.1002/anie.201307333

DO - 10.1002/anie.201307333

M3 - 文章

AN - SCOPUS:84889684547

SN - 1433-7851

VL - 52

SP - 13434

EP - 13438

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 50

ER -

Variable photophysical properties of phosphorescent iridium(III) complexes triggered by closo- and nido-carborane substitution

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Keywords

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