Visible-Light-Induced Meerwein Fluoroarylation of Styrenes

Hai Jun Tang; Bin Zhang; Fei Xue; Chao Feng

doi:10.1021/acs.orglett.1c01249

Visible-Light-Induced Meerwein Fluoroarylation of Styrenes

Hai Jun Tang, Bin Zhang, Fei Xue, Chao Feng

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

An unprecedented approach for assembling a broad range of 1,2-diarylethane derivatives with fluorine-containing fully substituted carbon centers was developed. The protocol features straightforward operation, proceeds under metal-free condition, and accommodates a large variety of synthetically useful functionalities. The critical aspect to the success of this novel transformation lies in using aryldiazonium salts as both aryl radical progenitor and also as single electron acceptor which elegantly enables a radical-polar crossover manifold.

Original language	English
Pages (from-to)	4040-4044
Number of pages	5
Journal	Organic Letters
Volume	23
Issue number	10
DOIs	https://doi.org/10.1021/acs.orglett.1c01249
State	Published - 21 May 2021

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abstract = "An unprecedented approach for assembling a broad range of 1,2-diarylethane derivatives with fluorine-containing fully substituted carbon centers was developed. The protocol features straightforward operation, proceeds under metal-free condition, and accommodates a large variety of synthetically useful functionalities. The critical aspect to the success of this novel transformation lies in using aryldiazonium salts as both aryl radical progenitor and also as single electron acceptor which elegantly enables a radical-polar crossover manifold.",

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Y1 - 2021/5/21

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AB - An unprecedented approach for assembling a broad range of 1,2-diarylethane derivatives with fluorine-containing fully substituted carbon centers was developed. The protocol features straightforward operation, proceeds under metal-free condition, and accommodates a large variety of synthetically useful functionalities. The critical aspect to the success of this novel transformation lies in using aryldiazonium salts as both aryl radical progenitor and also as single electron acceptor which elegantly enables a radical-polar crossover manifold.

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Visible-Light-Induced Meerwein Fluoroarylation of Styrenes

Abstract

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