@article{a0f14d2e1b2f42ed93dcc179f654a121,
title = "α-Nucleophilic Addition to α,β-Unsaturated Carbonyl Compounds via Photocatalytically Generated α-Carbonyl Carbocations",
abstract = "We report the photocatalytic oxidation of α-carbonyl radicals of amides or esters to the corresponding α-carbonyl carbocations through super photoreductant CBZ6 induced redox-neutral photocatalysis. The α-carbonyl radicals are formed by the β-addition of alkyl radicals generated in situ by the photocatalytic fragmentation of N-hydroxyphthalimide esters to the α,β-unsaturated amides and esters. This method enables the α-nucleophilic addition of hydroxyl or alkoxyl radicals to amides and esters without any prefunctionalization.",
keywords = "Organic photocatalysts, Oxidation, Photoredox catalysis, α,β-Unsaturated carbonyl compounds, α-Carbonyl carbocations",
author = "Zhang, {Chong Jin} and Yu Sun and Jie Gong and Hao Zhang and Liu, {Zhen Zhen} and Fang Wang and Chen, {Jin Xiang} and Qu, {Jian Ping} and Kang, {Yan Biao}",
note = "Publisher Copyright: {\textcopyright} 2024 Wiley-VCH GmbH.",
year = "2025",
month = jan,
day = "15",
doi = "10.1002/anie.202415496",
language = "英语",
volume = "64",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "3",
}