A new [4 + 1]/[4 + 2]bicycliaztion strategy for accessing functionalized indeno[1,2-b] pyran-2-ones

Bo Jiang; Rong Fu; Jiang Kai Qiu; Yan Yu; Shu Liang Wang; Shu Jiang Tu

doi:10.1039/c6ra16462e

A new [4 + 1]/[4 + 2]bicycliaztion strategy for accessing functionalized indeno[1,2-b] pyran-2-ones

Bo Jiang, Rong Fu, Jiang Kai Qiu, Yan Yu, Shu Liang Wang, Shu Jiang Tu

Jiangsu Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

4 引用（Scopus）

摘要

A new base-promoted bicyclization strategy for the synthesis of functionalized indeno[1,2-b]pyran-2-ones has been established from readily accessible o-phthalaldehydes (OPA) and the preformed 1-arylethylidenemalononitriles. The reaction pathway involves an aldol addition, 5-exo-trig carbocyclization and 6-exo-dig oxo-cyclization sequence, resulting in continuous multiple C-C and C-O bond formation.

源语言	英语
页（从-至）	74372-74375
页数	4
期刊	RSC Advances
卷	6
期	78
DOI	https://doi.org/10.1039/c6ra16462e
出版状态	已出版 - 2016
已对外发布	是

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abstract = "A new base-promoted bicyclization strategy for the synthesis of functionalized indeno[1,2-b]pyran-2-ones has been established from readily accessible o-phthalaldehydes (OPA) and the preformed 1-arylethylidenemalononitriles. The reaction pathway involves an aldol addition, 5-exo-trig carbocyclization and 6-exo-dig oxo-cyclization sequence, resulting in continuous multiple C-C and C-O bond formation.",

author = "Bo Jiang and Rong Fu and Qiu, {Jiang Kai} and Yan Yu and Wang, {Shu Liang} and Tu, {Shu Jiang}",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6ra16462e",

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AU - Jiang, Bo

AU - Fu, Rong

AU - Qiu, Jiang Kai

AU - Yu, Yan

AU - Wang, Shu Liang

AU - Tu, Shu Jiang

PY - 2016

Y1 - 2016

N2 - A new base-promoted bicyclization strategy for the synthesis of functionalized indeno[1,2-b]pyran-2-ones has been established from readily accessible o-phthalaldehydes (OPA) and the preformed 1-arylethylidenemalononitriles. The reaction pathway involves an aldol addition, 5-exo-trig carbocyclization and 6-exo-dig oxo-cyclization sequence, resulting in continuous multiple C-C and C-O bond formation.

AB - A new base-promoted bicyclization strategy for the synthesis of functionalized indeno[1,2-b]pyran-2-ones has been established from readily accessible o-phthalaldehydes (OPA) and the preformed 1-arylethylidenemalononitriles. The reaction pathway involves an aldol addition, 5-exo-trig carbocyclization and 6-exo-dig oxo-cyclization sequence, resulting in continuous multiple C-C and C-O bond formation.

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DO - 10.1039/c6ra16462e

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SN - 2046-2069

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SP - 74372

EP - 74375

JO - RSC Advances

JF - RSC Advances

IS - 78

ER -

A new [4 + 1]/[4 + 2]bicycliaztion strategy for accessing functionalized indeno[1,2-b] pyran-2-ones

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