A new single-ion polymer electrolyte based on polyvinyl alcohol for lithium ion batteries

Y. S. Zhu; X. J. Wang; Y. Y. Hou; X. W. Gao; L. L. Liu; Y. P. Wu; M. Shimizu

doi:10.1016/j.electacta.2012.08.114

A new single-ion polymer electrolyte based on polyvinyl alcohol for lithium ion batteries

Y. S. Zhu, X. J. Wang, Y. Y. Hou, X. W. Gao, L. L. Liu, Y. P. Wu, M. Shimizu

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194 引用（Scopus）

摘要

In this study, a novel single-ion conducting polymer electrolyte, lithium polyvinyl alcohol oxalate borate (LiPVAOB), from the reaction of poly(vinyl alcohol) (PVA) with different molar ratio of boric acid, oxalic acid and lithium carbonate was prepared. The prepared materials were characterized by Fourier transformation infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), thermogravimetry (TG), differential thermal analysis (DTA), electrochemical impedance spectroscopy (EIS) and linear sweep voltammetry. Ionic conductivity of these polymer electrolytes from adding an assistant (about 20 wt.% propylene carbonate) is dependent on molar ratio of the reactants and can up to 6.11 × 10^-6 S cm^-1 at ambient temperature. Their electrochemical window can be stable up to 7 V (vs. Li⁺/Li), which is of great attraction for high voltage lithium ion batteries with high energy density.

源语言	英语
页（从-至）	113-118
页数	6
期刊	Electrochimica Acta
卷	87
DOI	https://doi.org/10.1016/j.electacta.2012.08.114
出版状态	已出版 - 1 1月 2013
已对外发布	是

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title = "A new single-ion polymer electrolyte based on polyvinyl alcohol for lithium ion batteries",

abstract = "In this study, a novel single-ion conducting polymer electrolyte, lithium polyvinyl alcohol oxalate borate (LiPVAOB), from the reaction of poly(vinyl alcohol) (PVA) with different molar ratio of boric acid, oxalic acid and lithium carbonate was prepared. The prepared materials were characterized by Fourier transformation infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), thermogravimetry (TG), differential thermal analysis (DTA), electrochemical impedance spectroscopy (EIS) and linear sweep voltammetry. Ionic conductivity of these polymer electrolytes from adding an assistant (about 20 wt.% propylene carbonate) is dependent on molar ratio of the reactants and can up to 6.11 × 10-6 S cm-1 at ambient temperature. Their electrochemical window can be stable up to 7 V (vs. Li+/Li), which is of great attraction for high voltage lithium ion batteries with high energy density.",

keywords = "Borate, Lithium ion batteries, Poly(vinyl alcohol) (PVA), Polymer electrolytes, Single-ion conductor",

author = "Zhu, {Y. S.} and Wang, {X. J.} and Hou, {Y. Y.} and Gao, {X. W.} and Liu, {L. L.} and Wu, {Y. P.} and M. Shimizu",

year = "2013",

month = jan,

day = "1",

doi = "10.1016/j.electacta.2012.08.114",

language = "英语",

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journal = "Electrochimica Acta",

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TY - JOUR

T1 - A new single-ion polymer electrolyte based on polyvinyl alcohol for lithium ion batteries

AU - Zhu, Y. S.

AU - Wang, X. J.

AU - Hou, Y. Y.

AU - Gao, X. W.

AU - Liu, L. L.

AU - Wu, Y. P.

AU - Shimizu, M.

PY - 2013/1/1

Y1 - 2013/1/1

N2 - In this study, a novel single-ion conducting polymer electrolyte, lithium polyvinyl alcohol oxalate borate (LiPVAOB), from the reaction of poly(vinyl alcohol) (PVA) with different molar ratio of boric acid, oxalic acid and lithium carbonate was prepared. The prepared materials were characterized by Fourier transformation infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), thermogravimetry (TG), differential thermal analysis (DTA), electrochemical impedance spectroscopy (EIS) and linear sweep voltammetry. Ionic conductivity of these polymer electrolytes from adding an assistant (about 20 wt.% propylene carbonate) is dependent on molar ratio of the reactants and can up to 6.11 × 10-6 S cm-1 at ambient temperature. Their electrochemical window can be stable up to 7 V (vs. Li+/Li), which is of great attraction for high voltage lithium ion batteries with high energy density.

AB - In this study, a novel single-ion conducting polymer electrolyte, lithium polyvinyl alcohol oxalate borate (LiPVAOB), from the reaction of poly(vinyl alcohol) (PVA) with different molar ratio of boric acid, oxalic acid and lithium carbonate was prepared. The prepared materials were characterized by Fourier transformation infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), thermogravimetry (TG), differential thermal analysis (DTA), electrochemical impedance spectroscopy (EIS) and linear sweep voltammetry. Ionic conductivity of these polymer electrolytes from adding an assistant (about 20 wt.% propylene carbonate) is dependent on molar ratio of the reactants and can up to 6.11 × 10-6 S cm-1 at ambient temperature. Their electrochemical window can be stable up to 7 V (vs. Li+/Li), which is of great attraction for high voltage lithium ion batteries with high energy density.

KW - Borate

KW - Lithium ion batteries

KW - Poly(vinyl alcohol) (PVA)

KW - Polymer electrolytes

KW - Single-ion conductor

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U2 - 10.1016/j.electacta.2012.08.114

DO - 10.1016/j.electacta.2012.08.114

M3 - 文章

AN - SCOPUS:84869874721

SN - 0013-4686

VL - 87

SP - 113

EP - 118

JO - Electrochimica Acta

JF - Electrochimica Acta

ER -

A new single-ion polymer electrolyte based on polyvinyl alcohol for lithium ion batteries

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