A new vanadium sulfate with ferrimagnetic and NLO properties constructed from novel discrete umbrella-like [VV3-O)4VIV4O5(SO4)4(en)]5- anions

Shuai Zhou, Hongxiang Wan, Gonghao Hu, Yu Zhang, Ying Liu, Hao Miao, Dunru Zhu, Yan Xu

科研成果: 期刊稿件文章同行评审

13 引用 (Scopus)

摘要

A new vanadium sulfate, [H2N(CH3)2]19/3(en)[V5O53-O)4(SO4)4](SO4)2/3[HN(CH3)2]2/31, constructed from novel umbrella-like [VV3-O)4VIV4O5(SO4)4(en)]5- anions was synthesized and structurally characterized using single-crystal X-ray analysis. The magnetic and optical studies of 1 indicate that the title compound exhibits significant ZFS (zero field splitting), interesting ferrimagnetic interactions and strong two photon absorption.

源语言英语
页(从-至)8605-8608
页数4
期刊Dalton Transactions
44
18
DOI
出版状态已出版 - 14 5月 2015

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