A simple but efficient strategy to enhance hydrostability of intensely fluorescent Mg-based coordination polymer (CP) via forming a composite of CP with hydrophobic PVDF

Lu Zhai, Wen Wei Zhang, Jing Lin Zuo, Xiao Ming Ren

科研成果: 期刊稿件文章同行评审

9 引用 (Scopus)

摘要

A coordination polymer (CP) of Mg2+ with 1,3,5-benzenetricarboxylate (BTC3-) was synthesized using a solvothermal method. The Mg-CP, with a formula of Mg3(BTC)(HCOO)3(DMF)3, crystallizes in the trigonal space group P3, with cell parameters of a = b = 13.972(5) Å, c = 8.090(5) Å and V = 1367.6(11) Å3, and shows a lamella structure built from planar rosette-type hexanuclear architectures. The Mg-CP emits intense blue fluorescence arising from π∗ → π transition of intra-ligand of BTC3- with 21.69% quantum yield, yet it exhibits poor stability to water. The composites of Mg-CP with hydrophobic polyvinylidene fluoride (PVDF) were sequentially prepared by mechanically mixed, tableted and annealed processes, which showed good compatibility between Mg-CP and PVDF, high hydrostability, and intense blue emission. This study suggests a simple but efficient method to solve the drawbacks of some functional CPs unstable to water and to promote them as practical applications in the field of functional materials.

源语言英语
页(从-至)3372-3379
页数8
期刊Dalton Transactions
45
8
DOI
出版状态已出版 - 2016

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