A Two-Dimensional Inorganic-Organic Hybrid Solid of Manganese(II) Hydrogenophosphate Showing High Proton Conductivity at Room Temperature

Hai Rong Zhao; Chen Xue; Cui Ping Li; Kai Ming Zhang; Hong Bin Luo; Shao Xian Liu; Xiao Ming Ren

doi:10.1021/acs.inorgchem.6b01438

A Two-Dimensional Inorganic-Organic Hybrid Solid of Manganese(II) Hydrogenophosphate Showing High Proton Conductivity at Room Temperature

Hai Rong Zhao, Chen Xue, Cui Ping Li, Kai Ming Zhang, Hong Bin Luo, Shao Xian Liu, Xiao Ming Ren

化学与分子工程学院

科研成果: 期刊稿件 › 文章 › 同行评审

42 引用（Scopus）

摘要

The inorganic-organic hybrid metal hydrogenophosphate with a formula of (C₂H₁₀N₂)[Mn₂(HPO₄)₃](H₂O) (1) shows layered crystal structure. The inorganic anion layer is built from Mn₃O₁₃ cluster units, and the interlayer spaces are filled by the charge-compensated ethylenediammonium dications together with the lattice water molecules. The thermogravimetry, variable-temperature powder X-ray diffraction, and the proton conductance under anhydrous and moisture environments were investigated for 1, disclosing that 1 shows high thermal stability and high proton transport nature, and the proton conductivity reaches to 1.64 × 10^-3 S·cm^-1 under 99%RH even at 293 K. The high proton conductivity is related to the formation of denser H-bond networks in the lattice.

源语言	英语
页（从-至）	8971-8975
页数	5
期刊	Inorganic Chemistry
卷	55
期	17
DOI	https://doi.org/10.1021/acs.inorgchem.6b01438
出版状态	已出版 - 6 9月 2016

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title = "A Two-Dimensional Inorganic-Organic Hybrid Solid of Manganese(II) Hydrogenophosphate Showing High Proton Conductivity at Room Temperature",

abstract = "The inorganic-organic hybrid metal hydrogenophosphate with a formula of (C2H10N2)[Mn2(HPO4)3](H2O) (1) shows layered crystal structure. The inorganic anion layer is built from Mn3O13 cluster units, and the interlayer spaces are filled by the charge-compensated ethylenediammonium dications together with the lattice water molecules. The thermogravimetry, variable-temperature powder X-ray diffraction, and the proton conductance under anhydrous and moisture environments were investigated for 1, disclosing that 1 shows high thermal stability and high proton transport nature, and the proton conductivity reaches to 1.64 × 10-3 S·cm-1 under 99%RH even at 293 K. The high proton conductivity is related to the formation of denser H-bond networks in the lattice.",

author = "Zhao, {Hai Rong} and Chen Xue and Li, {Cui Ping} and Zhang, {Kai Ming} and Luo, {Hong Bin} and Liu, {Shao Xian} and Ren, {Xiao Ming}",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

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doi = "10.1021/acs.inorgchem.6b01438",

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T1 - A Two-Dimensional Inorganic-Organic Hybrid Solid of Manganese(II) Hydrogenophosphate Showing High Proton Conductivity at Room Temperature

AU - Zhao, Hai Rong

AU - Xue, Chen

AU - Li, Cui Ping

AU - Zhang, Kai Ming

AU - Luo, Hong Bin

AU - Liu, Shao Xian

AU - Ren, Xiao Ming

PY - 2016/9/6

Y1 - 2016/9/6

N2 - The inorganic-organic hybrid metal hydrogenophosphate with a formula of (C2H10N2)[Mn2(HPO4)3](H2O) (1) shows layered crystal structure. The inorganic anion layer is built from Mn3O13 cluster units, and the interlayer spaces are filled by the charge-compensated ethylenediammonium dications together with the lattice water molecules. The thermogravimetry, variable-temperature powder X-ray diffraction, and the proton conductance under anhydrous and moisture environments were investigated for 1, disclosing that 1 shows high thermal stability and high proton transport nature, and the proton conductivity reaches to 1.64 × 10-3 S·cm-1 under 99%RH even at 293 K. The high proton conductivity is related to the formation of denser H-bond networks in the lattice.

AB - The inorganic-organic hybrid metal hydrogenophosphate with a formula of (C2H10N2)[Mn2(HPO4)3](H2O) (1) shows layered crystal structure. The inorganic anion layer is built from Mn3O13 cluster units, and the interlayer spaces are filled by the charge-compensated ethylenediammonium dications together with the lattice water molecules. The thermogravimetry, variable-temperature powder X-ray diffraction, and the proton conductance under anhydrous and moisture environments were investigated for 1, disclosing that 1 shows high thermal stability and high proton transport nature, and the proton conductivity reaches to 1.64 × 10-3 S·cm-1 under 99%RH even at 293 K. The high proton conductivity is related to the formation of denser H-bond networks in the lattice.

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A Two-Dimensional Inorganic-Organic Hybrid Solid of Manganese(II) Hydrogenophosphate Showing High Proton Conductivity at Room Temperature

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