An: In situ element permeation constructed high endurance Li-LLZO interface at high current densities

Yang Lu; Xiao Huang; Yadong Ruan; Qingsong Wang; Rui Kun; Jianhua Yang; Zhaoyin Wen

doi:10.1039/c8ta07241h

An: In situ element permeation constructed high endurance Li-LLZO interface at high current densities

Yang Lu, Xiao Huang, Yadong Ruan, Qingsong Wang, Rui Kun, Jianhua Yang, Zhaoyin Wen

科研成果: 期刊稿件 › 文章 › 同行评审

182 引用（Scopus）

摘要

The construction of a solid/solid SEI is proposed to improve the endurance of LLZO solid electrolytes. Al will spontaneously permeate into LLZO and construct a robust Al enriched SEI by the reaction between Al₄Li₉ and LLZO, realizing a low interfacial impedance of <1 Ω cm², high endurance for 3000 h and a high critical current density of more than 0.9 and 2.3 mA cm^-2 at 25 °C and 60 °C, respectively.

源语言	英语
页（从-至）	18853-18858
页数	6
期刊	Journal of Materials Chemistry A
卷	6
期	39
DOI	https://doi.org/10.1039/c8ta07241h
出版状态	已出版 - 2018
已对外发布	是

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10.1039/c8ta07241h

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title = "An: In situ element permeation constructed high endurance Li-LLZO interface at high current densities",

abstract = "The construction of a solid/solid SEI is proposed to improve the endurance of LLZO solid electrolytes. Al will spontaneously permeate into LLZO and construct a robust Al enriched SEI by the reaction between Al4Li9 and LLZO, realizing a low interfacial impedance of <1 Ω cm2, high endurance for 3000 h and a high critical current density of more than 0.9 and 2.3 mA cm-2 at 25 °C and 60 °C, respectively.",

author = "Yang Lu and Xiao Huang and Yadong Ruan and Qingsong Wang and Rui Kun and Jianhua Yang and Zhaoyin Wen",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2018",

doi = "10.1039/c8ta07241h",

language = "英语",

volume = "6",

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T2 - In situ element permeation constructed high endurance Li-LLZO interface at high current densities

AU - Lu, Yang

AU - Huang, Xiao

AU - Ruan, Yadong

AU - Wang, Qingsong

AU - Kun, Rui

AU - Yang, Jianhua

AU - Wen, Zhaoyin

PY - 2018

Y1 - 2018

N2 - The construction of a solid/solid SEI is proposed to improve the endurance of LLZO solid electrolytes. Al will spontaneously permeate into LLZO and construct a robust Al enriched SEI by the reaction between Al4Li9 and LLZO, realizing a low interfacial impedance of <1 Ω cm2, high endurance for 3000 h and a high critical current density of more than 0.9 and 2.3 mA cm-2 at 25 °C and 60 °C, respectively.

AB - The construction of a solid/solid SEI is proposed to improve the endurance of LLZO solid electrolytes. Al will spontaneously permeate into LLZO and construct a robust Al enriched SEI by the reaction between Al4Li9 and LLZO, realizing a low interfacial impedance of <1 Ω cm2, high endurance for 3000 h and a high critical current density of more than 0.9 and 2.3 mA cm-2 at 25 °C and 60 °C, respectively.

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U2 - 10.1039/c8ta07241h

DO - 10.1039/c8ta07241h

M3 - 文章

AN - SCOPUS:85054828473

SN - 2050-7488

VL - 6

SP - 18853

EP - 18858

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 39

ER -

An: In situ element permeation constructed high endurance Li-LLZO interface at high current densities

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