Application of ionic liquids containing tricyanomethanide [C(CN) 3]- or tetracyanoborate [B(CN)4]- anions in dye-sensitized solar cells

Magdalena Marszalek; Zhaofu Fei; Dun Ru Zhu; Rosario Scopelliti; Paul J. Dyson; Shaik Mohammed Zakeeruddin; Michael Grätzel

doi:10.1021/ic201513m

Application of ionic liquids containing tricyanomethanide [C(CN) ₃]^- or tetracyanoborate [B(CN)₄]^- anions in dye-sensitized solar cells

Magdalena Marszalek, Zhaofu Fei, Dun Ru Zhu, Rosario Scopelliti, Paul J. Dyson, Shaik Mohammed Zakeeruddin, Michael Grätzel

化工学院

Swiss Federal Institute of Technology Lausanne

科研成果: 期刊稿件 › 文章 › 同行评审

98 引用（Scopus）

摘要

A series of novel ionic liquids composed of imidazolium, pyridinium, pyrrolidinium, and ammonium cations with tricyanomethanide or tetracyanoborate anions were prepared. The ionic liquids were characterized by NMR and IR spectroscopy and ESI-mass spectrometry, and their physical properties were investigated. Solid state structures of the N-propyl-N-methylpyrrolidinium and triethylpropylammonium tetracyanoborate salts were obtained by single crystal X-ray diffraction. The salts that are liquid at room temperature were evaluated as electrolyte additives in dye-sensitized solar cells, giving rise to efficiencies 7.35 and 7.85% under 100 and 10% Sun, respectively, in combination with the standard Z907 dye.

源语言	英语
页（从-至）	11561-11567
页数	7
期刊	Inorganic Chemistry
卷	50
期	22
DOI	https://doi.org/10.1021/ic201513m
出版状态	已出版 - 21 11月 2011

访问文件

10.1021/ic201513m

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{60fe1065634b4a939dc7685d4e9c711f,

title = "Application of ionic liquids containing tricyanomethanide [C(CN) 3]- or tetracyanoborate [B(CN)4]- anions in dye-sensitized solar cells",

abstract = "A series of novel ionic liquids composed of imidazolium, pyridinium, pyrrolidinium, and ammonium cations with tricyanomethanide or tetracyanoborate anions were prepared. The ionic liquids were characterized by NMR and IR spectroscopy and ESI-mass spectrometry, and their physical properties were investigated. Solid state structures of the N-propyl-N-methylpyrrolidinium and triethylpropylammonium tetracyanoborate salts were obtained by single crystal X-ray diffraction. The salts that are liquid at room temperature were evaluated as electrolyte additives in dye-sensitized solar cells, giving rise to efficiencies 7.35 and 7.85% under 100 and 10% Sun, respectively, in combination with the standard Z907 dye.",

author = "Magdalena Marszalek and Zhaofu Fei and Zhu, {Dun Ru} and Rosario Scopelliti and Dyson, {Paul J.} and Zakeeruddin, {Shaik Mohammed} and Michael Gr{\"a}tzel",

year = "2011",

month = nov,

day = "21",

doi = "10.1021/ic201513m",

language = "英语",

volume = "50",

pages = "11561--11567",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "22",

}

TY - JOUR

T1 - Application of ionic liquids containing tricyanomethanide [C(CN) 3]- or tetracyanoborate [B(CN)4]- anions in dye-sensitized solar cells

AU - Marszalek, Magdalena

AU - Fei, Zhaofu

AU - Zhu, Dun Ru

AU - Scopelliti, Rosario

AU - Dyson, Paul J.

AU - Zakeeruddin, Shaik Mohammed

AU - Grätzel, Michael

PY - 2011/11/21

Y1 - 2011/11/21

N2 - A series of novel ionic liquids composed of imidazolium, pyridinium, pyrrolidinium, and ammonium cations with tricyanomethanide or tetracyanoborate anions were prepared. The ionic liquids were characterized by NMR and IR spectroscopy and ESI-mass spectrometry, and their physical properties were investigated. Solid state structures of the N-propyl-N-methylpyrrolidinium and triethylpropylammonium tetracyanoborate salts were obtained by single crystal X-ray diffraction. The salts that are liquid at room temperature were evaluated as electrolyte additives in dye-sensitized solar cells, giving rise to efficiencies 7.35 and 7.85% under 100 and 10% Sun, respectively, in combination with the standard Z907 dye.

AB - A series of novel ionic liquids composed of imidazolium, pyridinium, pyrrolidinium, and ammonium cations with tricyanomethanide or tetracyanoborate anions were prepared. The ionic liquids were characterized by NMR and IR spectroscopy and ESI-mass spectrometry, and their physical properties were investigated. Solid state structures of the N-propyl-N-methylpyrrolidinium and triethylpropylammonium tetracyanoborate salts were obtained by single crystal X-ray diffraction. The salts that are liquid at room temperature were evaluated as electrolyte additives in dye-sensitized solar cells, giving rise to efficiencies 7.35 and 7.85% under 100 and 10% Sun, respectively, in combination with the standard Z907 dye.

UR - http://www.scopus.com/inward/record.url?scp=81255134892&partnerID=8YFLogxK

U2 - 10.1021/ic201513m

DO - 10.1021/ic201513m

M3 - 文章

AN - SCOPUS:81255134892

SN - 0020-1669

VL - 50

SP - 11561

EP - 11567

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 22

ER -

Application of ionic liquids containing tricyanomethanide [C(CN) 3]- or tetracyanoborate [B(CN)4]- anions in dye-sensitized solar cells

摘要

访问文件

其它文件与链接

指纹

引用此

Application of ionic liquids containing tricyanomethanide [C(CN) ₃]^- or tetracyanoborate [B(CN)₄]^- anions in dye-sensitized solar cells