Breaking the Isolated Pentagon Rule by Encapsulating Xe2 in C60: The Guest Defines the Shape of the Host

Said Jalife, Sukanta Mondal, José Luis Cabellos, Sudip Pan, Miguel Ángel Méndez-Rojas, Israel Fernández, Gernot Frenking, Gabriel Merino

科研成果: 期刊稿件文章同行评审

13 引用 (Scopus)

摘要

While many fullerenes obeying the isolated pentagon rule (IPR) are experimentally known, isomers which violate this rule may become accessible via endohedral encapsulation of a guest molecule. Density functional theory computations predict a lower energy of non-IPR endohedral noble gas fullerenes over IPR analogues, specifically when C60 encapsulates a Xe dimer! So, the guest defines the shape of the carbon fullerene.

源语言英语
页(从-至)2405-2408
页数4
期刊ChemistrySelect
1
10
DOI
出版状态已出版 - 1 7月 2016
已对外发布

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