Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex

Yong Chua Teo; Kui Thong Tan; Teck Peng Loh

doi:10.1039/b412736f

Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex

Yong Chua Teo, Kui Thong Tan, Teck Peng Loh

National University of Singapore

科研成果: 期刊稿件 › 文章 › 同行评审

72 引用（Scopus）

摘要

A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributyl stannanes to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in good yields and high enantioselectivities (90-96% ee).

源语言	英语
页（从-至）	1318-1320
页数	3
期刊	Chemical Communications
期	10
DOI	https://doi.org/10.1039/b412736f
出版状态	已出版 - 14 3月 2005
已对外发布	是

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10.1039/b412736f

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title = "Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex",

abstract = "A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributyl stannanes to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in good yields and high enantioselectivities (90-96% ee).",

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AU - Loh, Teck Peng

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N2 - A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributyl stannanes to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in good yields and high enantioselectivities (90-96% ee).

AB - A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributyl stannanes to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in good yields and high enantioselectivities (90-96% ee).

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U2 - 10.1039/b412736f

DO - 10.1039/b412736f

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SP - 1318

EP - 1320

JO - Chemical Communications

JF - Chemical Communications

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Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex

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