Comment on "revisiting π backbonding: The influence of d orbitals on metal-CO bonds and ligand red shifts" by D. Koch, Y. Chen, P. Golub and S. Manzhos,: Phys. Chem. Chem. Phys., 2019, 21, 20814

Sudip Pan, Gernot Frenking

科研成果: 期刊稿件文章同行评审

8 引用 (Scopus)

摘要

We challenge the statement of Koch et al. that the M → CO charge transfer and the decrease of the CO stretching frequency in metal carbonyl complexes do not depend on the metal d orbitals. The approach of the authors is severely flawed and leads to misleading conclusions.

源语言英语
页(从-至)5377-5379
页数3
期刊Physical Chemistry Chemical Physics
22
9
DOI
出版状态已出版 - 7 3月 2020

指纹

探究 'Comment on "revisiting π backbonding: The influence of d orbitals on metal-CO bonds and ligand red shifts" by D. Koch, Y. Chen, P. Golub and S. Manzhos,: Phys. Chem. Chem. Phys., 2019, 21, 20814' 的科研主题。它们共同构成独一无二的指纹。

引用此