Comment on “The oxidation state in low-valent beryllium and magnesium compounds” by M. Gimferrer, S. Danés, E. Vos, C. B. Yildiz, I. Corral, A. Jana, P. Salvador and D. M. Andrada, Chem. Sci. 2022, 13, 6583

Sudip Pan; Gernot Frenking

doi:10.1039/d2sc04231b

Comment on “The oxidation state in low-valent beryllium and magnesium compounds” by M. Gimferrer, S. Danés, E. Vos, C. B. Yildiz, I. Corral, A. Jana, P. Salvador and D. M. Andrada, Chem. Sci. 2022, 13, 6583

Sudip Pan, Gernot Frenking

化学与分子工程学院

科研成果: 期刊稿件 › 文献综述 › 同行评审

15 引用（Scopus）

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We challenge the assignment of the oxidation state +2 for beryllium and magnesium in the complexes Be(cAAC^Dip)₂ and Mg(cAAC^Dip)₂ as suggested by Gimferrer et al., Chem. Sci. 2022, 13, 6583 in a recent study. A careful review of the data in the ESI contradicts their own statement and shows that the results support the earlier suggestion that the metals are in the zero oxidation state. The authors reported wrong data for the excitation energies of Be and Mg to the ¹D (np²) state. We also correct some misleading statements about the EDA method.

源语言	英语
期刊	Chemical Science
DOI	https://doi.org/10.1039/d2sc04231b
出版状态	已接受/待刊 - 2022

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title = "Comment on “The oxidation state in low-valent beryllium and magnesium compounds” by M. Gimferrer, S. Dan{\'e}s, E. Vos, C. B. Yildiz, I. Corral, A. Jana, P. Salvador and D. M. Andrada, Chem. Sci. 2022, 13, 6583",

abstract = "We challenge the assignment of the oxidation state +2 for beryllium and magnesium in the complexes Be(cAACDip)2 and Mg(cAACDip)2 as suggested by Gimferrer et al., Chem. Sci. 2022, 13, 6583 in a recent study. A careful review of the data in the ESI contradicts their own statement and shows that the results support the earlier suggestion that the metals are in the zero oxidation state. The authors reported wrong data for the excitation energies of Be and Mg to the 1D (np2) state. We also correct some misleading statements about the EDA method.",

author = "Sudip Pan and Gernot Frenking",

note = "Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",

year = "2022",

doi = "10.1039/d2sc04231b",

language = "英语",

journal = "Chemical Science",

issn = "2041-6520",

publisher = "Royal Society of Chemistry",

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T1 - Comment on “The oxidation state in low-valent beryllium and magnesium compounds” by M. Gimferrer, S. Danés, E. Vos, C. B. Yildiz, I. Corral, A. Jana, P. Salvador and D. M. Andrada, Chem. Sci. 2022, 13, 6583

AU - Pan, Sudip

AU - Frenking, Gernot

PY - 2022

Y1 - 2022

N2 - We challenge the assignment of the oxidation state +2 for beryllium and magnesium in the complexes Be(cAACDip)2 and Mg(cAACDip)2 as suggested by Gimferrer et al., Chem. Sci. 2022, 13, 6583 in a recent study. A careful review of the data in the ESI contradicts their own statement and shows that the results support the earlier suggestion that the metals are in the zero oxidation state. The authors reported wrong data for the excitation energies of Be and Mg to the 1D (np2) state. We also correct some misleading statements about the EDA method.

AB - We challenge the assignment of the oxidation state +2 for beryllium and magnesium in the complexes Be(cAACDip)2 and Mg(cAACDip)2 as suggested by Gimferrer et al., Chem. Sci. 2022, 13, 6583 in a recent study. A careful review of the data in the ESI contradicts their own statement and shows that the results support the earlier suggestion that the metals are in the zero oxidation state. The authors reported wrong data for the excitation energies of Be and Mg to the 1D (np2) state. We also correct some misleading statements about the EDA method.

UR - http://www.scopus.com/inward/record.url?scp=85144735098&partnerID=8YFLogxK

U2 - 10.1039/d2sc04231b

DO - 10.1039/d2sc04231b

M3 - 文献综述

AN - SCOPUS:85144735098

SN - 2041-6520

JO - Chemical Science

JF - Chemical Science

ER -

Comment on “The oxidation state in low-valent beryllium and magnesium compounds” by M. Gimferrer, S. Danés, E. Vos, C. B. Yildiz, I. Corral, A. Jana, P. Salvador and D. M. Andrada, Chem. Sci. 2022, 13, 6583

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