Comment on "topological Analysis of the Electron Density in the Carbonyl Complexes M(CO)8(M = Ca, Sr, Ba)"

Nicole Holzmann, Israel Fernández, Gernot Frenking

科研成果: 期刊稿件文章同行评审

6 引用 (Scopus)

摘要

We question the statement of a recent publication (Organometallics 2020, 39, 132, DOI: 10.1021/acs.organomet.9b00699) that the M → CO πbackdonation in the alkaline earth carbonyl complexes M(CO)8 (M = Ca, Sr, Ba) is negligible and that the decrease of the CO stretching frequency is rather caused by interligand interactions of the carbonyl groups within the molecules.

源语言英语
页(从-至)2956-2958
页数3
期刊Organometallics
39
16
DOI
出版状态已出版 - 24 8月 2020

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