Copper-catalyzed highly regioselective silylcupration of terminal alkynes to form α-vinylsilanes

Peng Wang; Xue Liang Yeo; Teck Peng Loh

doi:10.1021/ja109464u

Copper-catalyzed highly regioselective silylcupration of terminal alkynes to form α-vinylsilanes

Peng Wang, Xue Liang Yeo, Teck Peng Loh

Nanyang Technological University

科研成果: 期刊稿件 › 文章 › 同行评审

117 引用（Scopus）

摘要

A highly regioselective synthesis of branched vinylsilanes through silicon-copper additions to terminal alkynes catalyzed by copper(I) was developed using methanol as additive. The corresponding vinylsilanes were obtained with excellent branched to linear selectivity of up to 99/1 in good yields.

源语言	英语
页（从-至）	1254-1256
页数	3
期刊	Journal of the American Chemical Society
卷	133
期	5
DOI	https://doi.org/10.1021/ja109464u
出版状态	已出版 - 9 2月 2011
已对外发布	是

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10.1021/ja109464u

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title = "Copper-catalyzed highly regioselective silylcupration of terminal alkynes to form α-vinylsilanes",

abstract = "A highly regioselective synthesis of branched vinylsilanes through silicon-copper additions to terminal alkynes catalyzed by copper(I) was developed using methanol as additive. The corresponding vinylsilanes were obtained with excellent branched to linear selectivity of up to 99/1 in good yields.",

author = "Peng Wang and Yeo, {Xue Liang} and Loh, {Teck Peng}",

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N2 - A highly regioselective synthesis of branched vinylsilanes through silicon-copper additions to terminal alkynes catalyzed by copper(I) was developed using methanol as additive. The corresponding vinylsilanes were obtained with excellent branched to linear selectivity of up to 99/1 in good yields.

AB - A highly regioselective synthesis of branched vinylsilanes through silicon-copper additions to terminal alkynes catalyzed by copper(I) was developed using methanol as additive. The corresponding vinylsilanes were obtained with excellent branched to linear selectivity of up to 99/1 in good yields.

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M3 - 文章

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Copper-catalyzed highly regioselective silylcupration of terminal alkynes to form α-vinylsilanes

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