@article{c317985bcd8042e78e41ec6bbf6298bf,
title = "Di- ortho-beryllated Carbodiphosphorane: A Compound with a Metal-Carbon Double Bond to an Element of the s-Block",
abstract = "Double bonds have been realized for a wide variety of elements in the p-, d-, and f-blocks. However, no s-block metal complexes with a double bond have been identified. Here we report the synthesis and characterization of a di-ortho-beryllated carbodiphosphorane, which exhibits a double dative Be═C bond. This species shows an unprecedented bonding situation at the metal center, which was extensively analyzed by experimental and computational means.",
author = "Buchner, {Magnus R.} and Sudip Pan and Christina Poggel and Nils Spang and Matthias M{\"u}ller and Gernot Frenking and J{\"o}rg Sundermeyer",
note = "Publisher Copyright: Copyright {\textcopyright} 2020 American Chemical Society.",
year = "2020",
month = sep,
day = "14",
doi = "10.1021/acs.organomet.0c00434",
language = "英语",
volume = "39",
pages = "3224--3231",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",
number = "17",
}